Chem. J. Chinese Universities ›› 1997, Vol. 18 ›› Issue (10): 1580.

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A Study of Hydrothermal Synthesis and Properties of Rare Earth-modified PbTiO3 Fine Powders

XIONG Rong1, CHENG Hu-Min1, MA Ji-Ming1, CHEN Shou-Liu2, ZHUANG Yong-Qiu2, ZHANG Pei-Lin3, ZHONG Wei-Lie3   

  1. 1. Institute of Physical Chemistry, Peking University Beijing 100871;
    2. Institute of Acoustics, Academic Sinica, Beijing 100080
  • Received:1996-01-06 Online:1997-10-24 Published:1997-10-24

Abstract: Lead titanate ceramics fine powders modified with several rare earth (La, Pr, Nd,Sin, Eu) were prepared by hydrothermal method. The transformation between tetragonal(ferroelectric) phase and cubic (paraelectric) phase for the La-doped PbTiO3 solid solutionwas investigated. Curie' temperature of the PTsolid solution with x(La)=0. 04 and y(Mn)=0. 01 was ca. 400 ℃. The dependences between rare earth-doping content and piezoelectricproperties of PTsolid solutions were determined. The d33, increased, while g33, kt and kt/kpecreased with increasing rare earth-doping content in PTsolid solutions.

Key words: Lead titanate, Hydrothermal synthesis, Piezoelectric ceramics, Rare earth, Solid solution

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