Studies on the Kinetics of the Reaction of C60 and C70 with Benzoyl Peroxide

Abstract

Abstract: The kinetics of the reaction of C₆₀ and C₇₀ with benzoyl peroxide is studied.The results show that the reaction is first order against fullerenes and the rate constants at 342.2K,348.2K, 353.2 Kand 358.2 Kwere calculated and they are in agreement with experimental results.The rate constant of C₇₀ is greater than that of C₆₀ and this indicated that C₇₀is more actived than C₆₀.The activation energies are 9.275×10⁴J/mol and 8.438×10⁴J/mol for C₆₀ and C₇₀ respectively.

Key words: C₆₀, C₇₀, Kinetics

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HU Bo, XUE Wan-Hua, ZHANG Fa-Yi, SHANG Zhen-Feng, MA Ke-Qin, ZANG Ya-Ru, ZHAO Xue-Zhuang. Studies on the Kinetics of the Reaction of C₆₀ and C₇₀ with Benzoyl Peroxide[J]. Chem. J. Chinese Universities, 1996, 17(6): 917.

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Studies on the Kinetics of the Reaction of C₆₀ and C₇₀ with Benzoyl Peroxide

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