Chem. J. Chinese Universities ›› 1996, Vol. 17 ›› Issue (5): 693.
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BAI Jie-Ling, NI Yong-Nian
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Abstract: Synthetic pigments,such as amaranth,sunset yellow,tartrazine and ponceau 4R,have sensitive adsorptive voltammograms in a phosphate buffer(pH=5.7).The voltammetric waves of these pigments,however,are seriously overlapped and it is difficult to determine them without a preseparation,In this paper,the experimental conditions were investigated.The mixture was accumulated for 240 s at a HMDEwith a accumulate potential,-100 mV.After a 10 s quiet time the potential was then scanned from -100 to -100 mVusing linear sweep voltammetry(LSV) with a scan rate,100 mV/s.The voltammetric data of mixed pigments were processed by a chemometric approach,iterative target transformation factor analysis(ITTFA)and acceptable results with a total prediction error,8.35%,were obtained.
Key words: Adsorpative voltammetry, Pigment, Iterative target transformation factor analysis
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BAI Jie-Ling, NI Yong-Nian. Adsorptive Voltammetric Determination of Mixed Pigment by Iterative Target Transformation Factor Analysis[J]. Chem. J. Chinese Universities, 1996, 17(5): 693.
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http://www.cjcu.jlu.edu.cn/EN/Y1996/V17/I5/693