Synthesis, Structure and Spectral Properties of Fe-doped DyInO3 Yellow Pigments†

doi:10.7503/cjcu20170673

Abstract

Abstract:

A series of Fe-doped DyInO₃ yellow pigments was prepared by a traditional high temperature solid-state method, and further characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), Raman spectroscopy and UV-Vis-NIR diffuse reflectance spectroscopy. The results show that all the samples are of pure hexagonal structure (space group: P6₃cm). With Fe content increasing, the color of the samples change from yellow to orange. Diffuse reflectance spectroscopy results indicate that the as-prepared yellow pigments have excellent NIR reflectance(the reflectance is up to 90%), which demonstrates these pigments could reduce solar heat effectively.

Key words: Hexagonal structure, Yellow pigment, Fe-doping, Infrared reflectance

CLC Number:

O611

TrendMD:

ZHANG Yimeng, YUAN Long, LIU Huanhuan, HOU Changmin. Synthesis, Structure and Spectral Properties of Fe-doped DyInO₃ Yellow Pigments^†[J]. Chem. J. Chinese Universities, 2018, 39(7): 1400.

Figures/Tables 10

Fig.1 XRD patterns of DyIn1-xFexO3(A) and enlarged part of samples(B)^a. DyInO3; b. DyIn0.9Fe0.1O3; c. DyIn0.8Fe0.2O3.^The enlarged (112) peaks are shown for clarity.

Fig.2 XRD refinement results of DyIn1-xFexO3^(A) DyInO3; (B) DyIn0.9Fe0.1O3; (C) DyIn0.8Fe0.2O3.

Fig.3 Lattice parameter variation in DyIn1-xFexO3 samples(x=0, 0.1, 0.2)

Table 1 Structure refinement parameters of the DyIn1-xFexO3(x=0, 0.1, 0.2)

Sample	Space group	Lattice parameter			V/(nm³)	R_wp(%)	R_p(%)
Sample	Space group	a/nm	b/nm	c/nm	V/(nm³)	R_wp(%)	R_p(%)
DyInO₃	P6₃cm	0.6309(3)	0.6309(3)	1.2310(0)	0.4243(9)	5.69	8.19
DyIn_0.9Fe_0.1O₃	P6₃cm	0.6266(1)	0.6266(1)	1.2211(8)	0.4152(4)	9.65	5.88
DyIn_0.8Fe_0.2O₃	P6₃cm	0.6247(1)	0.6247(1)	1.2173(2)	0.4114(3)	7.92	5.70

Fig.4 SEM images(A—C) and EDX spectra(D—F) of DyIn1-xFexO3 samples^ (A), (D) DyInO3; (B), (E) DyIn0.9Fe0.1O3; (C), (F) DyIn0.8Fe0.2O3.

Fig.5 Raman spectra of DyIn1-xFexO3 samples^ a. DyInO3; b. DyIn0.9Fe0.1O3; c. DyIn0.8Fe0.2O3.^ The arrows denote additional peaks.

Fig.6 A typical 3D CIE color space(A) and photographs under a standard illuminant D65 of DyIn1-xFexO3 powder(B—D)

Fig.7 Diffuse reflectance spectra of the DyIn1-xFexO3 samples^a. DyInO3; b. DyIn0.9Fe0.1O3; c. DyIn0.8Fe0.2O3.

Fig.8 Solar spectral irradiance based on combined direct and circumsolar effects

Fig.9 UV-Vis-NIR reflectance spectra of DyIn1-xFexO3 samples^ Commercial TiO2 is shown for comparison.

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Synthesis, Structure and Spectral Properties of Fe-doped DyInO₃ Yellow Pigments^†

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