Development in Study on Reaction of Alkanethiol (Arenethiol)or Their Salts with Iron Carbonyls──Synthesis, Structure and Reaction of Nucleophilic Anionsof the Type [(μ-CO)(μ-RS)Fe2(CO)6]-

Abstract

Abstract: The synthesis, structure and reactions of the new type of butterfly-shaped anioniccomplex salts M⁺[μ-CO) (μ-RS)Fe₂(CO)₆]^-(M⁺=Et₃NH⁺,Li⁺,Na⁺,MgX⁺) have beenreviewed.The complex salts were usually prepared by the action of alkanethiolates orarenethiolates RS-M⁺ on Fe₃(CO)₁₂ in THFand used in situ for subsequent reactions.Thesingle-crystal X-ray diffraction analysis confirmed that this kind of compsplex salts had a butterfly-shaped framework consisting of Fe₂SCatoms.The complex salts are highly reactivetowards diverse electrophilic substrates.Such substrates, generally, include unsaturatedalkyl halides,acid chlorides,alkynes,halides of phosphorus and arsenic,carbon disulfide,sulfur(1) chloride, elemental sulfur and selenium and alkylmercuric chlorides etc..Apparently,such a kind of anionic complex salts has become a very effective reagent and has beenused extensively in the syntheses of novel organometallic and cluster complexes.

Key words: Complex anions [(μ-CO)(μ-RS)Fe₂(CO)₆]^-, Nucleophilic reactions, Bridged Fe/S complexes, Synthesis, Structures

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SONG Li-Cheng. Development in Study on Reaction of Alkanethiol (Arenethiol)or Their Salts with Iron Carbonyls──Synthesis, Structure and Reaction of Nucleophilic Anionsof the Type [(μ-CO)(μ-RS)Fe₂(CO)₆]^-[J]. Chem. J. Chinese Universities, 1996, 17(4): 575.

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Development in Study on Reaction of Alkanethiol (Arenethiol)or Their Salts with Iron Carbonyls──Synthesis, Structure and Reaction of Nucleophilic Anionsof the Type [(μ-CO)(μ-RS)Fe₂(CO)₆]^-

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