Synthesis and Characterization of Layered Double Hydroxides Pillared with Peroxoheteropolyanions

Abstract

Abstract: Pillared layered double hydroxides(LDH),Zn₂Al(OH)₆-SiW₁₁(TiO₂)O₃₉ and Zn₂Al(OH)₆-SiW₉(TiO₂)₃O₃₇ were synthesized by direct ion-exchange reaction in aqueous solution,and characterized by elementary analysis,XRD,IR and XPS spectra.The interlayer spaces of the pillared products increase from 0.92 nm to 1.47 nm with the peroxoheteropolyanions displacing the NO₃^- ions in the gallery.The results from IR,XPS and chemical analysis show that the structures of peroxoheteropolyanions are well remained.

Key words: Peroxoheteropolyanion, Intercalation, Pillared hydrotalcites

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HUA Rui-Nian, SHAN Qiu-Jie, GONG Jian, Qu Lun-Yu. Synthesis and Characterization of Layered Double Hydroxides Pillared with Peroxoheteropolyanions[J]. Chem. J. Chinese Universities, 1996, 17(10): 1500.

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Synthesis and Characterization of Layered Double Hydroxides Pillared with Peroxoheteropolyanions

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