Room-Temperature Fluorescence of C60-Glycine Ester Derivatives in Solution

Chem. J. Chinese Universities ›› 1995, Vol. 16 ›› Issue (10): 1512.

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Room-Temperature Fluorescence of C₆₀-Glycine Ester Derivatives in Solution

ZHOU De-Jian, GAN Liang-Bing, TAN Hai-Song, LUO Chu-Ping, YAO Guang-Qing, HUANG Chun-Hui

State Key Laboratory of Rare Earth Material Chemistry and Applications, Peking University, Beijing, 100871

Received:1995-02-15 Revised:1995-04-21 Online:1995-10-24 Published:1995-10-24

Abstract

Abstract: Two new C₆₀-glycine ester derivatives C₆₀(EtOOCCHNHCHCOOEt)(A) and C₆₀(PbCH₂OOCCHNHCHCOOCH₂Ph)(B) were synthesized and purified. Their room temperature photoluminescence was measured for the first time from their CHCl₃solutions.It was first observed for fullerenes that their fluorescence could be quenched by concentration. The fluorescence lifetime was determined to be 1.5±0.3 ns for sA and 1.6±0.3 ns for B, respectively, using the frequency-domain method.

Key words: C₆₀-Glycine ester derivative, Concentration quenching, Fluorescence lifetime

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ZHOU De-Jian, GAN Liang-Bing, TAN Hai-Song, LUO Chu-Ping, YAO Guang-Qing, HUANG Chun-Hui. Room-Temperature Fluorescence of C₆₀-Glycine Ester Derivatives in Solution[J]. Chem. J. Chinese Universities, 1995, 16(10): 1512.

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Room-Temperature Fluorescence of C₆₀-Glycine Ester Derivatives in Solution

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