Studies on Solid State Reactions of Coordination Chemistry(LXV)─The Solid State Reactions of Copper Acetate Monohydrate with Schiff Bases at Room Temperature

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (8): 1110.

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Studies on Solid State Reactions of Coordination Chemistry(LXV)─The Solid State Reactions of Copper Acetate Monohydrate with Schiff Bases at Room Temperature

LIN Jian-Jun, ZHENG Li-Min, Fu Yan, XIN Xin-Quan

Department of Chemistry, Coordination Chemistry State Key Laboratory, Coordination Chemictry Institution, Nanjing University, Nanjing, 210008

Received:1993-11-30 Revised:1994-01-27 Online:1994-08-24 Published:1994-08-24

Abstract

Abstract: The solid state reactions of Cu(Oac)₂, H₂Owith two schiff bases:o-[(o-hydroxybenzylidene)amino] pyridine(HSAPy)and o-[(o-hydroxybenzylidene)amino ] phenol (H₂SAP) have been investigated at room temperature.The solid products were characterized by means of elemental analysis, XRD, DTA, UVand magnetic susceptibility. The activation energies, obtained by employing isothermal electrical conductivity method, increase in the order:H₂SAP(35. 25KJ/mol<HSAPy(82. 31KJ/mol).The effect of the structures of ligands on the solid state reaction is discussed.

Key words: Copper acetate monohydrate, Schiff base, Solid state reaction

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LIN Jian-Jun, ZHENG Li-Min, Fu Yan, XIN Xin-Quan. Studies on Solid State Reactions of Coordination Chemistry(LXV)─The Solid State Reactions of Copper Acetate Monohydrate with Schiff Bases at Room Temperature[J]. Chem. J. Chinese Universities, 1994, 15(8): 1110.

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Studies on Solid State Reactions of Coordination Chemistry(LXV)─The Solid State Reactions of Copper Acetate Monohydrate with Schiff Bases at Room Temperature

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