Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts

Chem. J. Chinese Universities ›› 1994, Vol. 15 ›› Issue (10): 1489.

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Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts

GUI Ming-De, JIANG Du-Xiao, ZHU Shen-Jie

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1993-12-28 Revised:1994-04-13 Online:1994-10-24 Published:1994-10-24

Abstract

Abstract: Six different 5, 10, 15, 20-tetrakis(2-alkylphenyl)porphyrins(T_(O-R)PPH₂)and their ferric complex salts T_(O-R)PPFeCl(R=Me, Et, n-Pr, i-Pr, n-Bu, t-Bu)were synthesized.Besides R=Me is known, all others are new compounds.We found that T_(O-i-Pr)PPH₂, T_(O-t-Bu)PPH₂, and T_(O-i-Pr)PPFeCl, T_(O-t-Bu)PPFeCl were more difficult to formation than other T_(O-R)PPH₂ and T_(O-R)TTPFeCl.Their IRand UV-Vis spectra were determined and the relationship between the structures and the spectral properties was discussed.

Key words: T_(O-R)PPFeCl, Steric effect, Synthesis, Spectral property

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GUI Ming-De, JIANG Du-Xiao, ZHU Shen-Jie . Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts[J]. Chem. J. Chinese Universities, 1994, 15(10): 1489.

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Synthesis and Spectra Determination of 5,10,15,20-Tetrakis-(2-alkylphenyl)porphyrins and Their Ferric Complex Salts

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