Synthesis, Crystal Structure and Properties of TAAB Nickel Adducts with Axial N-Base Ligands

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (6): 745.

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Synthesis, Crystal Structure and Properties of TAAB Nickel Adducts with Axial N-Base Ligands

LI Ming-Xing¹, XU Zheng¹, LI Jin-Yu¹, YOU Xiao-Zeng¹, WANG Hua-Qin¹, YANG Yue¹, YU Yun-Peng², ZHU Duo-Lin²

1. Coordination Chemistry Institute, Coordination Chemistry State Key Laboratory, Center for Materials Analysis, Nanjing University, Nanjing, 210008;
2. Department of Chemistry, Zhenjiang Normal College, Zhenjiang, 212003

Received:1992-10-05 Revised:1992-11-29 Online:1993-06-24 Published:1993-06-24

Abstract

Abstract: Four adducts of Py, Im, DMFand 4,4'-bipy with Ni(TAAB)²⁺, where TAAB=tetraben-zo[b,f,j,R][1,5,9,13]tetraazacyclohexadecine, were synthesized and characterized by elementary analysis, IRand thermal analysis.The crystal structure of [Ni(TAAB)(Py)₂](BF₄)₂has been determined.The crystal belongs to a monoclinic system with space group P2₁/n, α=1.6465(6) nm, b=1.2486(5) nm, c=2.0219(1) nm,β=113.79°, V=3.8039 nm³, Z=4, R=0.068.TAABmacrocyclic ligand presents a decidedly saddle-shaped appearance.The planes of two pyridine molecules are perpendicular to each other.The bond distances of Ni-N(n)(n=10,20,30,40) are in the range of 0.1983-0.2043 nm while the bond distances of Ni-N(B)(n=5,6) are 0.2182-0.2189 nm, forming a distorted octahedron coordination geometry around nickel ion.The variable-temperature magnetic susceptibility of 4,4'-bipyridine-bridging nickel TAABcomplex obeys the Curi-er-Weiss law (θ=- 44 K) and indicates an antiferromagnetic exchange interaction between nickel ions.

Key words: Axial coordination, TAAB macrocyclic, Nickel complex, Crystal structure, Magnetic exchange interaction

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LI Ming-Xing, XU Zheng, LI Jin-Yu, YOU Xiao-Zeng, WANG Hua-Qin, YANG Yue, YU Yun-Peng, ZHU Duo-Lin. Synthesis, Crystal Structure and Properties of TAAB Nickel Adducts with Axial N-Base Ligands[J]. Chem. J. Chinese Universities, 1993, 14(6): 745.

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Synthesis, Crystal Structure and Properties of TAAB Nickel Adducts with Axial N-Base Ligands

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