Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (2): 164.

• Articles • Previous Articles     Next Articles

Synthesis and Characterization of Binuclear Complexes of Cu(Ⅱ), Ni(Ⅱ) with Schiff Bases Macrocyclic Ligand Derived form N-Oxide-2,6-Diformylpyridine and 1,3-Propanediamine

YAN Shi-Ping, CHENG Peng, XIA Qing, XU Hong-Shan, JIANG Zong-Hui, LIAO Dai-Zheng, WANG Geng-Lin   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1992-03-31 Revised:1992-10-16 Online:1993-02-24 Published:1993-02-24

Abstract: The title complexes, Cu2L(ClO4)C2H5OH·H2O, Ni2L(ClO4)·4H2O(Lis the macrocyclic ligand) were synthesized from N-oxide-2, 6-diformylpyridine and Ⅰ, 3-propanediamine by using Cu(Ⅱ) ions and Ni(Ⅱ)ions as the templating metal ions.The new compounds were characterized by elementary analysis, 1R, ESRand magnetism.

Key words: Binuclear complex, Macrocyclic complex.Magnetism, N-oxide

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