The Solvent Effect of Epichlorohydrin Ring-Opening Reaction Catalysized by Zeolite

Chem. J. Chinese Universities ›› 1993, Vol. 14 ›› Issue (11): 1553.

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The Solvent Effect of Epichlorohydrin Ring-Opening Reaction Catalysized by Zeolite

LIU Fu-An, LI Yao-Xian, LIU Zai-Qon

Department of Chemistry, Jilin University, Changchun, 130023

Received:1992-12-03 Revised:1993-06-14 Online:1993-11-24 Published:1993-11-24

Abstract

Abstract: This paper reports the kinetics of ring-opening reaction of epichlorohydrin with propi-onic acid catalyzed by HZSM-5 exchanged with Fe(Ⅲ).The reaction of epichlorohydrin with propionic acid is the first-order.The rate equation is v=k[epichlorohydrin] when the amount of Fe-ZSM-5 is fixed.The influence of benzene, toluene ο-chlorotoluene, m-chlorotoluene, p-chlorotoluene or o-nitrotoluene as solvent on the rate of the reaction is also investigated.Through the mathematical treatment, the relationship between lnk and dielectric constant ε is found to be Ink=2.80[(ε - 1)/(2ε + 1)] - 9.63 (except o-nitrotoluene)

Key words: Zeolite catalyst, Epoxide compound, Solvent effect

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LIU Fu-An, LI Yao-Xian, LIU Zai-Qon . The Solvent Effect of Epichlorohydrin Ring-Opening Reaction Catalysized by Zeolite[J]. Chem. J. Chinese Universities, 1993, 14(11): 1553.

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The Solvent Effect of Epichlorohydrin Ring-Opening Reaction Catalysized by Zeolite

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