Effect of Carbonyl Groups in Charge Transfer Complex and Determination of Complex Stoichiometry

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (7): 1002.

• Articles • Previous Articles Next Articles

Effect of Carbonyl Groups in Charge Transfer Complex and Determination of Complex Stoichiometry

DONG Yu-ping¹, FENG Lin-xian¹, YANG Shi-lin¹, SHEN Jia-cong²

1. Department of Chemistry, Zhejiang University, Hangzhou, 310027;
2. Department of Chemistry, Jilin University

Received:1991-07-05 Online:1992-07-24 Published:1992-07-24

Abstract

Abstract: The report researched the effect of carbonyl groups in charge transfer complex by means of NMR, in which succinic anhydride was taken for a model compound of maleic anhydride, and complex stoichiometries of succinic anhydride-styrene, succinic anhydride-N-vinylcar-bazole were determined through amendment of Hanna-Ashbaugh equation.The experiment results indicate that carbonyl groups were easier to participate in complex reactions than olefinic groups.

Key words: Charge transfer complex reaction, Model compound, Complex stoichiometry

TrendMD:

DONG Yu-ping, FENG Lin-xian, YANG Shi-lin, SHEN Jia-cong. Effect of Carbonyl Groups in Charge Transfer Complex and Determination of Complex Stoichiometry[J]. Chem. J. Chinese Universities, 1992, 13(7): 1002.

[1]	TANG Haiyan, ZHAO Maoshuang, FENG Li, CAO Zexing. Theoretical Studies on the Taking off of Oxygen-containing Functional Groups in Lignite Model Compounds^† [J]. Chem. J. Chinese Universities, 2014, 35(11): 2370.
[2]	HUANG Yu-Cheng, WANG Su-Fan*, JU Xue-Hai, DU Jin-Yan, ZHOU Tao, YE Shi-Yong. Theoritical Studies on the Pyrolysis Mechanism of Pyridazine [J]. Chem. J. Chinese Universities, 2009, 30(5): 1005.
[3]	CAO Jian, DING Hong, NA Hui, LI Xian-Feng, ZHANG Chun-Ling, WU Zhong-Wen . Synthesis of Oligomers for PEDEK with Different Endgroups [J]. Chem. J. Chinese Universities, 2003, 24(8): 1503.
[4]	KE Yang-Chuan, WU Zhong-Wen, ZHENG Yu-Bin, SUN Jia-Zhong. Studies on Poly (aryl ether ether ketone )s Structure and Its Chain Reaction by Quantum Calculation of Its Model Compound [J]. Chem. J. Chinese Universities, 1995, 16(9): 1426.
[5]	HAN De-Yan, CHEN Hui-Lan, WU Qin-Yuan, ZHOU Jin-Suo, TANG Wen-Xia . Studies on Coenzyme B₁₂ Model Compounds(Ⅵ)─The Influence of Axial and Equatorial Ligands on the Stabilities or Co-C Bonds of RCo(salen)L and RCo(SB)Complexes [J]. Chem. J. Chinese Universities, 1994, 15(5): 637.
[6]	LIU Ai-Min, ZHOU Tai-Jin, WAN Hui-Lin, TSAI Khi-Rui. Structural Information of Nitrogenase Active-Center Clusters Deduced from EHMO Study [J]. Chem. J. Chinese Universities, 1993, 14(7): 996.
[7]	LIAO Zhan-ru, HUANG Yan, SHI Ju-en, LU Chang-lin. The Superoxide Dismutase Activity of Binuclear Model Compounds Containing Copper (Ⅱ), Iron(Ⅲ) and Manganese (Ⅱ) [J]. Chem. J. Chinese Universities, 1992, 13(5): 697.
[8]	JIANG Yi-Qin, LIU Wan-Qiao, TANG Kai-Qing, LIAO Zhan-Ru, CHEN Pei-Ling, SHI Ju-En . The Determination of Dismutation Rate Constant of Superoxide Ion Catalyzed by SOD Model Compound with Tast Polarography [J]. Chem. J. Chinese Universities, 1992, 13(11): 1444.
[9]	Chen Hui-lan, Chen Guan-qing, Miao Bing-wen, Tang Wen-xia . Studies on Coenzyme B₁₂Model Compounds (Ⅲ)--The Synthesis of a Kind of New Alkylcobalt Schiff Base Complexes and Their Stabilities of the Co-C Bond [J]. Chem. J. Chinese Universities, 1991, 12(4): 431.
[10]	Luo Qinhui, Shen Mengchang, Gao Wei, Peng Qingyun . A Study on Reaction Kinetics of Superoxide Dismutase and Its Model Compounds with Superoxide Ion by Illumination [J]. Chem. J. Chinese Universities, 1990, 11(9): 928.

Effect of Carbonyl Groups in Charge Transfer Complex and Determination of Complex Stoichiometry

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 10

Recommended Articles

Metrics

Comments