Application of Reflectance Thin-layer Spectroelectrochemical Method

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (6): 741.

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Application of Reflectance Thin-layer Spectroelectrochemical Method

ZOU Ming-zhu, SHENG Gui-hua, ZHENG Yan-sheng

Department of Chemistry, Jilin University, Changchun, 130023

Received:1991-05-29 Online:1992-06-24 Published:1992-06-24

Abstract

Abstract: With ferrocene and methylene blue in nonaqueous solvents, we tested the characteristic of the reflectance thin-layer spectroelectrochcmical cell which was designed by ourselves.We observed a very good response of optical signal to electrosignal.We determined the E^0' and n values of ferrocene and the diffusion coefficients of potassium ferrocyanide and methylene blue.The mechanism of methylene blue being reduced in DMSOmedium was investigated.

Key words: Reflectance thin-layer cell, Ferrocene, Methylene blue, Spectroelectrochemical method

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ZOU Ming-zhu, SHENG Gui-hua, ZHENG Yan-sheng . Application of Reflectance Thin-layer Spectroelectrochemical Method[J]. Chem. J. Chinese Universities, 1992, 13(6): 741.

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Application of Reflectance Thin-layer Spectroelectrochemical Method

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