Synthesis and Crystal Structure of [Bu4N]2[W2Ag3S8(C6H5CSS)] with Dithiobenzoic Acid as the Ligand

Abstract

Abstract: The title compound was prepared from the reaction of (NH₄)₂WS₄, AgNO₃, (Bu₄N)⁺(C₆H₅CSS)^- and Bu₄NBr in CH₃CN solution, then crystalized in CH₃CN/MeOH.It crystalizes in monoclinic space group P2₁/c with the following crystal parameters, a =1.8945 (12) nm, b=1.1963(10) nm, c=2.5660(14)nm, β=98.13(5)°, V=5.757(6) nm³, D_c=1.830 g/cm³, Z=4.The final R=0.0827 for 3329 reflections.The W₂Ag₃ unit in the anion W₂Ag₃S₈(C₆H₅CSS) forms a five-membered ring.

Key words: W-Ag-S cluster complex, Dithiobenzoic acid, Synthesis, Crystal structure

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JIN Xiang-lin, NI Hai-hong, TANG Ka-luo, TANG You-qi . Synthesis and Crystal Structure of [Bu₄N]₂[W₂Ag₃S₈(C₆H₅CSS)] with Dithiobenzoic Acid as the Ligand[J]. Chem. J. Chinese Universities, 1992, 13(6): 724.

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Synthesis and Crystal Structure of [Bu₄N]₂[W₂Ag₃S₈(C₆H₅CSS)] with Dithiobenzoic Acid as the Ligand

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