Interfacial Chemistry and Kinetics-Controlled Reaction Mechanism of Organo-Phosphoric Acid Mixed Extraction Systems

Abstract

Abstract: The interfacial chemistry for D2EHPA(Di(2-ethyl-hexyl) phosphoric acid)-M₁PAor M₂PA(two monophosphoric acid extractants with a long-chain)-Al³⁺ and D2EHPA-MEHPA (mono(2-cthyl hexyl)phosphoric acid)-Al³⁺ mixed extraction systems was studiedIt was found that, compared with individual extraction system alone, the mixed extraction systems show a particular advantage improvement in the interfacial characteristics of the systemsThe extraction kinetics and interfacial chemistry study indiate that the process of aluminium extraction by micella mixed extraction system(D2EHPA-M₁PA) is controlled by the chemical reaction in combination with diffusion, while the controlling reaction occurred inside the micella phase.

Key words: Extraction kinetics, Aluminum, Interfacial activity, Micellization

TrendMD:

YU Jing-fen, JI Chen . Interfacial Chemistry and Kinetics-Controlled Reaction Mechanism of Organo-Phosphoric Acid Mixed Extraction Systems[J]. Chem. J. Chinese Universities, 1992, 13(2): 224.

[1]	TAO Xingfu, HAN Chenglong, YANG Yang, LIU Kun. Synthesis of Aluminum Nanoparticles@Polymer Core-shell Nanostructures by Surface-initiated Polymerization [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220367.
[2]	LI Haibo, XIAO Changfa, JIANG Long, HUANG Yun, DAN Yi. Copolymerization of Methyl Acrylate and 1-Octene Catalyzed by the Loaded Aluminum Chloride on MCM-41 Molecular Sieve [J]. Chem. J. Chinese Universities, 2021, 42(9): 2974.
[3]	WANG Yuxiang, YU Shen, LIU Zhan, LYU Jiamin, LI Xiaoyun, CHEN Lihua, SU Baolian. One-step Synthesis of Amorphous Silica Aluminum Support Materials with Controllable Acidity and Porosity and Catalytic Performance of Their Pd-based Catalysts [J]. Chem. J. Chinese Universities, 2021, 42(6): 1826.
[4]	CHEN Liangdan,ZOU Wei,WU Liang,XIA Fanjie,HU Zhiyi,LI Yu,SU Baolian. Nano-Al₂O₃ Coated Li-rich Cathode Material Li_{1. 2}Ni_0.13Co_0.13Mn_0.54O₂ for Highly Improved Lithium-ion Batteries ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1329.
[5]	WANG Gang,WANG Keliang,LU Chunjing,WANG Ying. Preparation and Foam Properties of Janus Particles^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 990.
[6]	LIU Tuanchun, TANG Shaokun, JI Xiaowei, HAN Pei. Synthesis of Al₂O₃ Nanofibers with Ionic Liquids as Both the Template and Aluminum Source^† [J]. Chem. J. Chinese Universities, 2016, 37(5): 817.
[7]	HUANG Qingdong, LI Chunlan, ZHANG Yu, CUI Lishan, ZHU Baichun, YI Jianjun, LIU Lin, HAO Haijun. Synthesis and Catalytic Activity of Aluminum Complexes Supported by Bis(β-ketimine) and Bis(β-diketimine) Ligands^† [J]. Chem. J. Chinese Universities, 2014, 35(3): 524.
[8]	WENG Qiang, CHEN Pei, ZHAO Fengqi, GAO Hongxu, CHEN Xinbing, AN Zhongwei. Synthesis and Characterization of Hierarchical Aluminum Free Beta Zeolite^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 215.
[9]	ZHAO Binyu, LIANG Xiaojuan, CHEN Zhaoping, XIE Cuiping, LUO Le, ZHANG Zhimin, ZHONG Jiasong, XIANG Weidong. Studies on Optical Properties and Ce Concentration of Ce∶YAG Single Crystal for WLEDs^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 230.
[10]	YUAN Jing, ZHAI Xueru, XU Guiying, TAN Yebang, ZHANG Jian. Influence of Inorganic Salts on the Demulsification of Block Polyether with Seven Branches for Crude Oil Emulsion^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 325.
[11]	LI Liangyi, LI Zhanwei, FU Cuiliu, SUN Zhaoyan, AN Lijia. Computer Simulation of Micellization for Ring-like Block Copolymers^† [J]. Chem. J. Chinese Universities, 2014, 35(1): 168.
[12]	ZHANG Zhi-Min, LIANG Xiao-Juan, ZHAO Bin-Yu, CHEN Zhao-Ping, LIU Bing-Feng, ZHONG Jia-Song, XIANG Wei-Dong, LÜ Chun-Yan. Growth and Luminescence Properties of Ce,Mn: YAG Single Crystal [J]. Chem. J. Chinese Universities, 2013, 34(8): 1826.
[13]	XIE Yu, LÜ Zhong-Yuan, SUN Zhao-Yan, AN Li-Jia. Dissipative Particle Dynamics Simulation Study on the Micellization and Gelation Behavior of PEO-PPO-PEO Solution [J]. Chem. J. Chinese Universities, 2013, 34(6): 1454.
[14]	ZHU Yan-Li, JIAO Qing-Jie, HUANG Hao, REN Hui. Effect of Aluminum Particle Size on Thermal Decomposition of AP [J]. Chem. J. Chinese Universities, 2013, 34(3): 662.
[15]	ZHOU Ying-Jie, ZHU Hai-E, ZHANG Jun, WU Shui-Lin, YI Chang-Feng, XU Zu-Shun. Preparation and Micellization Behavior of Europium-containing Fluorescent Amphiphilic Graft Copolymer [J]. Chem. J. Chinese Universities, 2013, 34(3): 732.

Interfacial Chemistry and Kinetics-Controlled Reaction Mechanism of Organo-Phosphoric Acid Mixed Extraction Systems

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments