Graft Copolymerization of Styrene with Unsaturated Side Groups-Containing Polyoxyethylene and Properties of the Products

Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (12): 1613.

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Graft Copolymerization of Styrene with Unsaturated Side Groups-Containing Polyoxyethylene and Properties of the Products

XIE Hong-Quan¹, ZHANG Cong-Yun¹, GUO Jun-Shi¹, LIU Yong²

1. Department of Chemistry, Huazhong University of Science and Techmology, Wuhan, 430074;
2. Hebei Research Institute of Chemistry, Wuhan

Received:1991-12-16 Revised:1992-04-02 Online:1992-12-24 Published:1992-12-24

Abstract

Abstract: Graft copolymerization of styrene with copolymer of ethylene oxide and allyl glycidyl ether was studied.The graft efficiency can reach about 50%.The crude products were purified with extractions and characterized with IRand ¹H NMR.The complexes of the graft copolymers with LiClO₄ exhibit a conductivity approaching 10^-4 S/cm at 25℃ The graft copolymers possess good emulsifying property and phase transfer catalytic property in Williamson reaction.

Key words: Graft copolymer, Amphiphilic copolymer, Solid polymer electrolyte, Phase transfer catalyst, Polyoxyethylene

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XIE Hong-Quan, ZHANG Cong-Yun, GUO Jun-Shi, LIU Yong. Graft Copolymerization of Styrene with Unsaturated Side Groups-Containing Polyoxyethylene and Properties of the Products[J]. Chem. J. Chinese Universities, 1992, 13(12): 1613.

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Graft Copolymerization of Styrene with Unsaturated Side Groups-Containing Polyoxyethylene and Properties of the Products

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