Surface and Interfacial Properties of Polyoxyethylene Ether-type Surfactants†

doi:10.7503/cjcu20140113

Abstract

Abstract:

A series of poly nonylphenol polyoxyethylene ether nonionic surfactants with different polymerization degerees was synthesized with nonyl phenol and formaldehyde. The structures were characterized by infrared spectroscopy and nuclear magnetic resonance. Moreover, the surface properties were evaluated using the surface tension method. It is found that critical micelle concentration(cmc) of monomer, dimer and trimer incease with increasing of the number of hydrophilic group epoxyethane(EO) of the surfactants. In the case of the same number of EO, the cmc of surfactants were significantly reduce with the increase of the degree of polymerization. Although dimer and trimer show good surface properties, the surface property of trimer is more excellent than dimer. Moreover, dimer and trimer show more excellent adsorption and dispersion performance because the arrangments of them on the air/water boundary are significantly more compacted than dimer.

Key words: Polyoxyethylene ether surfactant, Critical micelle concentration, Surface tension

CLC Number:

O631

TrendMD:

HUANG Hailong, LI Hongyu, ZHANG Lei, REN Tianrui. Surface and Interfacial Properties of Polyoxyethylene Ether-type Surfactants^†[J]. Chem. J. Chinese Universities, 2014, 35(6): 1330.

Figures/Tables 9

References 42

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Sample	HLB	lgN	Sample	HLB	lgN
NP-10	11.95	1.07	NP-7	10.21	1.03
2NP-10	10.54	1.08	2NP-7	7.40	0.87
3NP-10	9.84	1.01	3NP-7	6.76	0.85
NP-9	11.73	1.06	NP-4	8.26	0.98
2NP-9	10.21	1.01	2NP-4	7.11	0.83
3NP-9	9.44	0.96	3NP-4	3.41	0.58

Sample	HLB	lgN	Sample	HLB	lgN
NP-10	11.95	1.07	NP-7	10.21	1.03
2NP-10	10.54	1.08	2NP-7	7.40	0.87
3NP-10	9.84	1.01	3NP-7	6.76	0.85
NP-9	11.73	1.06	NP-4	8.26	0.98
2NP-9	10.21	1.01	2NP-4	7.11	0.83
3NP-9	9.44	0.96	3NP-4	3.41	0.58

Sample	10^-5 cmc/(mol·L^-1)	γ_cmc/(mN·m^-1)	π_cmc/(mN·m^-1)	c₂₀/(mg·L^-1)	pc₂₀
NP-10	26.67	31.43	39.37	6.450	3.574
2NP-10	6.50	30.36	40.14	2.150	4.187
3NP-10	3.31	30.22	40.58	2.105	4.480
NP-9	26.30	31.34	39.46	6.330	3.580
2NP-9	6.49	30.33	40.27	2.110	4.188
3NP-9	3.24	30.49	40.59	2.100	4.491
NP-7	20.10	29.66	41.54	1.720	3.697
2NP-7	4.87	28.64	42.37	1.290	4.313
3NP-7	1.08	28.38	42.74	1.266	4.968
NP-4	14.94	28.24	42.67	0.960	3.825
2NP-4	3.71	27.56	43.50	0.480	4.431
3NP-4	0.66	27.17	43.97	0.320	5.211

Sample	10^-5 cmc/(mol·L^-1)	γ_cmc/(mN·m^-1)	π_cmc/(mN·m^-1)	c₂₀/(mg·L^-1)	pc₂₀
NP-10	26.67	31.43	39.37	6.450	3.574
2NP-10	6.50	30.36	40.14	2.150	4.187
3NP-10	3.31	30.22	40.58	2.105	4.480
NP-9	26.30	31.34	39.46	6.330	3.580
2NP-9	6.49	30.33	40.27	2.110	4.188
3NP-9	3.24	30.49	40.59	2.100	4.491
NP-7	20.10	29.66	41.54	1.720	3.697
2NP-7	4.87	28.64	42.37	1.290	4.313
3NP-7	1.08	28.38	42.74	1.266	4.968
NP-4	14.94	28.24	42.67	0.960	3.825
2NP-4	3.71	27.56	43.50	0.480	4.431
3NP-4	0.66	27.17	43.97	0.320	5.211

Sample	Γ_max/(g·cm^-2)	A_cmc/nm²	ΔG/(kJ·mol^-1)(298 K)	Sample	Γ_max/(g·cm^-2)	A_cmc/nm²	ΔG/(kJ·mol^-1)(298 K)
NP-10	1.56	1.08	-20.38	NP-7	1.41	1.19	-21.09
2NP-10	1.31	1.29	-23.88	2NP-7	1.17	1.43	-24.60
3NP-10	1.20	1.40	-25.56	3NP-7	1.03	1.67	-28.34
NP-9	1.55	1.10	-20.43	NP-4	1.31	1.28	-21.82
2NP-9	1.27	1.31	-23.89	2NP-4	1.09	1.53	-25.28
3NP-9	1.19	1.40	-25.61	3NP-4	0.98	1.82	-29.72