Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (10): 1197.

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Syntheses and Spectroscopic Properties of Ternary Complex (这里有图片19921002-1197-1.gif)

ZHAI Ying-Li, WANG Xiu-Jian, WANG Qiu-Ying   

  1. Department of Chemistry, Lanzhou University, Lanzhou, 730000
  • Received:1991-11-26 Revised:1992-02-23 Online:1992-10-24 Published:1992-10-24

Abstract: The ternary complex of monomolybdenum   was synthesized in methanol with o-mercaptophenol and benzoylhydrazine as the ligand and (Bu4N[Mo8O26] as the parent The properties of the complex were characterized by elemental analysis,molar conductivity,electronic spectra,infrared spectra,1H NMR spectra and TG-DTA,The most possible structure is proposed on the basis of the spectral data and the IR spectra show that the complex has not terminal oxygen atoms,

Key words: Molybdenum complex, Molybdenum-Sulfur bond, Molybdenum-Nitrogen bond, Synthesis

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