Studies on Organoarsenic Compounds(XV)--Synthesis of (4-Ethoxycarbonylphenyl)rnethyltriphenylarsonium Bromide and Its Reaction with α,β-Unsaturated Ketones Under Phase Transfer Condition

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (5): 625.

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Studies on Organoarsenic Compounds(XV)--Synthesis of (4-Ethoxycarbonylphenyl)rnethyltriphenylarsonium Bromide and Its Reaction with α,β-Unsaturated Ketones Under Phase Transfer Condition

Tao Wen-tian, Zeng Wu-zong

Department of Chemistry, Wuhan University, Wuhan, 430072

Received:1989-12-01 Online:1991-05-24 Published:1991-05-24

Abstract

Abstract: This paper presents the synthesis of (4-ethoxycarbonylphenyl) methyltriphenylarsonium bromide(1) and its reaction at room temperature with α,β-unsaturated ketones(2_a-r) in the two phase system of CH₂Cl₂-50% NaOH(aq) to afford the substituted cyclopropane derivatives(3_a-f), and the yields are fairly good (80-87%). Their structures are ascertained by elemental analysis, 1R,¹H NMR, and MS spectrometry.

Key words: Quarternary arsonium salts, Synthesis, Phase transfer, Substituted cyclopropane

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Tao Wen-tian, Zeng Wu-zong . Studies on Organoarsenic Compounds(XV)--Synthesis of (4-Ethoxycarbonylphenyl)rnethyltriphenylarsonium Bromide and Its Reaction with α,β-Unsaturated Ketones Under Phase Transfer Condition[J]. Chem. J. Chinese Universities, 1991, 12(5): 625.

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Studies on Organoarsenic Compounds(XV)--Synthesis of (4-Ethoxycarbonylphenyl)rnethyltriphenylarsonium Bromide and Its Reaction with α,β-Unsaturated Ketones Under Phase Transfer Condition

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