Synthesis and Structure of 1,1'- (Tetramethyldisilandiyl) η5-Dicyclopentadienyl Zirconium Dibromide

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (4): 488.

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Synthesis and Structure of 1,1'- (Tetramethyldisilandiyl) η⁵-Dicyclopentadienyl Zirconium Dibromide

Wang Ying¹, Zhou Xiu-zhong¹, Yao Xin-kai², Wang Hong-gen²

1. Department of Chemistry, Nankin University, Tianjin, 300071;
2. Central Laboratory of Nankai University, Tianjin

Received:1989-11-15 Online:1991-04-24 Published:1991-04-24

Abstract

Abstract: The title compound was prepared by acidolysis of μ-O-bis[1, 1'-(tetramethyldisilandiyl) η⁵-dicyclopentadienyl chlorozirconium] with concentrated hydrobromic acid. It' s structure was confirmed by X-ray diffraction method. The crystal is monoclinic, space group P2₁/n, with α=1. 1880(1) nm, 6=1.8739(2) nm, c=0. 8370(1) nm, β=98.37(1)°, V=1.8434 nm³, Z=4, final R=0. 054. Some selected bond lengths and bond angels have been compared with related compounds.

Key words: Acidolysis, Monoclinic system, Single crystal

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Wang Ying, Zhou Xiu-zhong, Yao Xin-kai, Wang Hong-gen. Synthesis and Structure of 1,1'- (Tetramethyldisilandiyl) η⁵-Dicyclopentadienyl Zirconium Dibromide[J]. Chem. J. Chinese Universities, 1991, 12(4): 488.

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Synthesis and Structure of 1,1'- (Tetramethyldisilandiyl) η⁵-Dicyclopentadienyl Zirconium Dibromide

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