Synthesis and Crystal Structure of a Bis-PPh3 Substituted Iron-Sulfur Cluster Complex(μ-n-C4H9S)(μ-CH3OCOCH2CH2S)Fe2(CO)4(PPh3)2

Abstract

Abstract: Reaction of triphenylphosphine with(μ-n-C₄H₉S)(μ-CH₃OCH₂CH₂S)Fe₂(CO)₆,whichwas prepared from a conjugated addition reaction of(μ-BrMgS)(μ-n-C₄H₉S)Fe₂(CO)₆ with,CH₂=CHOCH₃ followed by an alcoholysis process,gave the title complex of (μ-n-C₄H₉S)·(μ-CH₃OCH₂CH₂S).The crystals of the title complex are monoclinic, spacegroup C2/c,with α=30.892(4)Å,b=12.454(2)Å,c=25.725(4)Å;β=91.46(1)°,V=9893.7Å³;Z=8;D_c=1.284g/cm³;R=0.060. The cluster core of this complex consists of twoiron and two sulfur atoms with a butterfly configuration. Two triphenyl phosphine ligands are trans to Fe-Fe bent bond. The substituents are attached to sulfur atoms by e-bonds.

Key words: Triphenylphosphine, Fe-S clusters, Synthesis, Crystal structure

TrendMD:

Wang Ruji, Song Licheng, Wang Honggen, Hu Qingmei . Synthesis and Crystal Structure of a Bis-PPh₃ Substituted Iron-Sulfur Cluster Complex(μ-n-C₄H₉S)(μ-CH₃OCOCH₂CH₂S)Fe₂(CO)₄(PPh₃)₂[J]. Chem. J. Chinese Universities, 1990, 11(8): 832.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[9]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[10]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[11]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[12]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[13]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[14]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[15]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.

Synthesis and Crystal Structure of a Bis-PPh₃ Substituted Iron-Sulfur Cluster Complex(μ-n-C₄H₉S)(μ-CH₃OCOCH₂CH₂S)Fe₂(CO)₄(PPh₃)₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments