IRMPD Mechanism Study of Heterocyclic Compounds

Abstract

Abstract: The infrared multiphoton dissociation (IRMPD) of 1,4-dioxane, pyrrolidine and thiophene were studied with TEA CO₂ laser. The mechanism involving breakage of carbon and heteroatom bonds were explored. The dependence of dissociation yield on laser energy was obtained. The laser dissociation threshold energy for dioxane, pyrrolidine and thiophene are 0. 85, 1.0 and 1. 5 J/cm² respectively.

Key words: The infrared multiphoton dissociation, 1,4-Dioxane, Pyrrolidine, Thiophene

TrendMD:

An Xinyue, Guo Yongyou, Gu Yueshu, Liu Chuanpu, Hou Zhenglin, Yin Yongjia . IRMPD Mechanism Study of Heterocyclic Compounds[J]. Chem. J. Chinese Universities, 1990, 11(5): 501.

References

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