Studies on Some μ3-Oxo-bridged Trinuclear Manganese (Ⅲ)Schif f Base Complexes

Abstract

Abstract: Seven recently synthesized *3-oxo-bridged trinuclear Manganese(Ⅲ ) schiff base complexes-Mn₃O(bzaea)₂(C₂H₃O₂)₃, Mn₃O(bzaea)₂(C₂H₃O₂)₂(NCS), Mn₃O(bzaea)₃ClO₄ · 2H₂O, Mn₃O · (bzaea)₂(C₂H₃O₂)₂Br, Mn₃O(bzaea)₃I · 2H₂O, Mn₃O(bzaea)₂(C₂H₃O₂)₂NO₃ and Mn₃O(bzaea)₂ (C₂H₃O₂)₂BPh₄ · 3H₂O, where bzaea²-is the dianion of tridentate schiff base 2- (β-hydroxyethyl-imine)-4-phenyl-butanone(4), were studied by using the elemental analysis, electronic conductivity, magnetic susceptibity, thermal analysis, electronic and infrared spectra etc. The possible configurations of the complexes are suggested.

Key words: Manganese(Ⅲ), Schiff base, μ₃-Oxo-briged trinuclear complex

TrendMD:

Chen Ke, Chen Banglin . Studies on Some μ₃-Oxo-bridged Trinuclear Manganese (Ⅲ)Schif f Base Complexes[J]. Chem. J. Chinese Universities, 1990, 11(5): 443.

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Studies on Some μ₃-Oxo-bridged Trinuclear Manganese (Ⅲ)Schif f Base Complexes

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