Studies on Synthesis and Crystal Structure of Binuclear Complexes PdW(μ-Ph2Ppy)2(μ-CO)(CO)2Cl2 · 0. 7CH2Cl2

Chem. J. Chinese Universities ›› 1990, Vol. 11 ›› Issue (3): 255.

• Articles • Previous Articles Next Articles

Studies on Synthesis and Crystal Structure of Binuclear Complexes PdW(μ-Ph₂Ppy)₂(μ-CO)(CO)₂Cl₂ · 0. 7CH₂Cl₂

Zhang Zhengzhi¹, Wang Xukun¹, Shen Yujun¹, Yao Xinkan², Wang Honggen²

1. Institute of Elementoorganic Chemistry, Nankai University, Tianjin;
2. Centre of Measurement and Computation, Nankai University, Tianjin

Received:1988-11-04 Online:1990-03-24 Published:1990-03-24

Abstract

Abstract: 0CF.((, Anew complex containing Pd-Wbond, PdW(μ-Ph₂Ppy)₂(μ-CO)(CO)₂Cl₂ has been prepared and its crystal and molecular structure determined by X-ray diffraction. The molecule crystallized in the monoclinic space group P2₁/c with a=14. 616(3) Å, b=15. 289(1) Å, c=17. 676 (1) Å, β=97. 29(1)° and Z=4. the final R=0. 081. The palladium atom is d⁹ five-coordinated and the tungsten atom is d⁵ seven-coordinated. Both metal atoms possess the formal oxidation state +1. The molecule is chiral and belongs to the C₁ point group.

Key words: Pd-W binuclear complex, Synthesis, Crystal structure

TrendMD:

Zhang Zhengzhi, Wang Xukun, Shen Yujun, Yao Xinkan, Wang Honggen. Studies on Synthesis and Crystal Structure of Binuclear Complexes PdW(μ-Ph₂Ppy)₂(μ-CO)(CO)₂Cl₂ · 0. 7CH₂Cl₂[J]. Chem. J. Chinese Universities, 1990, 11(3): 255.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[3]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	SHI Naike, ZHANG Ya, SANSON Andrea, WANG Lei, CHEN Jun. Uniaxial Negative Thermal Expansion and Mechanism in Zn（NCN） [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220124.
[9]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[10]	LIU Qingqing, WANG Pu, WANG Yongshuai, ZHAO Man, DONG Huanli. Synthesis and Topochemical Polymerization Study of Naphthalene/perylene Imides Substituted Diacetylene Derivatives [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220091.
[11]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[12]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[13]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[14]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[15]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.

Studies on Synthesis and Crystal Structure of Binuclear Complexes PdW(μ-Ph₂Ppy)₂(μ-CO)(CO)₂Cl₂ · 0. 7CH₂Cl₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments