Synthesis and Crystal Structure of HMTTeF·I2 and Its Solid State Properties

Chem. J. Chinese Universities ›› 1988, Vol. 9 ›› Issue (8): 819.

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Synthesis and Crystal Structure of HMTTeF·I₂ and Its Solid State Properties

Li Zhushi¹, Jin Zhongsheng², Hu Ninghai², Liu Yongsheng²

1. Department of Chemistry, Yanbian University, Yanji;
2. Changchun Institute of Applied Chemistry, Aeademia Siniea, Changchun

Received:1987-02-10 Online:1988-08-24 Published:1988-08-24

Abstract

Abstract: The crystal of the salt HMTTeF·I₂ was obtained by electrolysis in the diphase mixture solution. It crystallizes in the monodinic space group P2₁/n, with Z = 4. Lattice parameters are: a=10.942(2), 6=14.294(2), c= 11.415(2)Å, β= 104.32(1)°. Ionization takes place on a pair of lone electrons of tellurium atom. The electrical conductivity (powder/pellet) at room temperature is 4.1×10^-5 Scm^-1. In this paper the relationship between the structure and the properties of HMTTeF.I₂ was discussed.

Key words: Organic conductor, Salt HMTTeF·I₂, Synthesis, Crystal structure, Raman spectrum

TrendMD:

Li Zhushi, Jin Zhongsheng, Hu Ninghai, Liu Yongsheng. Synthesis and Crystal Structure of HMTTeF·I₂ and Its Solid State Properties[J]. Chem. J. Chinese Universities, 1988, 9(8): 819.

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Synthesis and Crystal Structure of HMTTeF·I₂ and Its Solid State Properties

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