Preparation of CeO2-modified V-NiFeP bifunctional catalyst and its electrolytic performance of seawater

doi:10.7503/cjcu20250201

Chem. J. Chinese Universities

• Article • Previous Articles Next Articles

Preparation of CeO₂-modified V-NiFeP bifunctional catalyst and its electrolytic performance of seawater

CAI Qi¹, ZHANG Lingjie¹, ZHAO Fang², YANG Yang², YU Jing¹

1. College of Materials Science and Chemical Engineering，Harbin Engineering University 2. Huaneng Yichun Thermal Power Co., Ltd,

Received:2025-07-19 Revised:2025-09-04 Online First:2025-09-10 Published:2025-09-10
Contact: Jing YU E-mail:jing.yu@hrbeu.edu.cn
Supported by:
Supported by the Fundamental Research Funds of the Central University, China(No. 3072025YC1007)

Abstract

Abstract: In this paper, CeO₂-modified vanadium-doped porous nickel-iron phosphide nanosheet catalyst electrodes (V-NiFeP@CeO₂) were in-situ grown on nickel foam substrates through hydrothermal method, phosphating treatment, element doping and electrodeposition. V doping increased the number of active sites, and phosphorization could adjust the electronic structure. The interface interaction between CeO₂ and V-NiFeP was conducive to electron transfer and reactant adsorption, thereby enhancing the catalytic activity. The hydrogen evolution and oxygen evolution performance of the prepared bifunctional catalyst in alkaline solution and alkaline seawater solution were studied. The results of full water electrolysis tests showed that the required cell voltage of the catalyst at a current density of 100 mA·cm-2 in alkaline solution and alkaline seawater solution was only 1.83 and 1.85 V, respectively, along with stable operation for 27 h at a current density of 10 mA·cm-2 without voltage decay. The results exhibit V-NiFeP@CeO₂ has excellent electrocatalytic performance and long-term durability.

Key words: Transition metal phosphides, CeO₂, Electrolysis of seawater, Hydrogen evolution reaction, Oxygen evolution reaction

CLC Number:

O643

TrendMD:

CAI Qi, ZHANG Lingjie, ZHAO Fang, YANG Yang, YU Jing. Preparation of CeO₂-modified V-NiFeP bifunctional catalyst and its electrolytic performance of seawater[J]. Chem. J. Chinese Universities, doi: 10.7503/cjcu20250201.

[1]	YANG Siwei, HUANG Xuri. Theoretical Study of B， N Co-doped Fullerene C₇₀ as Non-metal Electrocatalysts for Oxygen Reduction and Evolution [J]. Chem. J. Chinese Universities, 2025, 46(4): 20240490.
[2]	GAO Fengyu, CHEN Du, LUO Ning, YAO Xiaolong, DUAN Erhong, YI Honghong, ZHAO Shunzheng, TANG Xiaolong. Catalytic Performance and Reaction Mechanism of Chlorobenzene Oxidation over MnO _x -CeO₂ Catalyst [J]. Chem. J. Chinese Universities, 2023, 44(4): 20220690.
[3]	WANG Mingzhi, ZHENG Yanping, WENG Weizheng. Catalytic Methane Combustion over CeO₂ Supported PdO and Ce_1‒_x Pd _x O_2‒_δ Species [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210816.
[4]	MA Jun, ZHONG Yang, ZHANG Shanshan, HUANG Yijun, ZHANG Lipeng, LI Yaping, SUN Xiaoming, XIA Zhenhai. Design and Theoretical Calculation of Heteroatoms Doped Graphdiyne Towards Efficiently Catalyzing Oxygen Reduction and Evolution Reactions [J]. Chem. J. Chinese Universities, 2021, 42(2): 624.
[5]	CHANG Jianhong, XU Guojie, LI Hui, FANG Qianrong. Quinone-based Covalent Organic Frameworks for Efficient Oxygen Evolution Reaction^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1609.
[6]	JIN E,SONG Kaixu,CUI Lili. Preparation and Electrocatalytic Performance of Carbon Material Co-doped by Bimetal Phosphide and Heteroatom ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1362.
[7]	LIU Lu,WU Hanyue,LI Jing,SHE Lan. Tuning Microstructures of Iron-Nickel Alloy Catalysts for Efficient Oxygen Evolution Reaction ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1083.
[8]	JIN Xin, FENG Xilan, LIU Dapeng, SU Yutong, ZHANG Zheng, ZHANG Yu. Auto-redox Strategy for the Synthesis of Co₃O₄/CeO₂ Nanocomposites and Their Structural Optimization Towards Catalytic CO Oxidation [J]. Chem. J. Chinese Universities, 2020, 41(4): 652.
[9]	JIANG Yuanyuan, LI Boyu, LU Yizhong, WU Tongshun, HAN Dongxue. Oxygen Evolution Reaction Electrocatalytic Performance Analysis of Electroless Plated Ni-B_x [J]. Chem. J. Chinese Universities, 2020, 41(12): 2774.
[10]	REN Xiangrong,ZHOU Qi. Preparation of Nanoporous Ni and NiO and Their Electrocatalytic Activities for Oxygen Evolution Reaction ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 162.
[11]	Long TIAN,Yan LONG,Shuyan SONG,Cheng WANG. Synthesis of Flower-like Structured Mn/CuO-CeO₂ and the Catalytic Performance for CO Oxide Reaction ^† [J]. Chem. J. Chinese Universities, 2019, 40(12): 2549.
[12]	ZHANG Min, CHEN Mengwei, GAO Hong, BI Yanfeng. Synthesis, Structure and Electrochemical Properties of Sulfonylcalix[4]arene Supported Co₁₆ Cluster ^† [J]. Chem. J. Chinese Universities, 2019, 40(10): 2052.
[13]	JIANG Yilan, YUAN Long, WANG Xiyang, HUANG Keke, FENG Shouhua. Effect of Defect Tuning on the Catalytic Behavior of Perovskite Structure Lanthanum Manganite^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 416.
[14]	LI Weilun, YAO Ying, ZHANG Cunzhong. Applications of Carbon Fiber Ultra-microelectrode and Powder Microelectrode in Exploring Influences of Non-aqueous Solvents and Cathode Materials on ORR and OER^† [J]. Chem. J. Chinese Universities, 2017, 38(4): 642.
[15]	FENG Xiaolei, QU Zongkai, CHEN Jun, WANG Dengdeng, CHEN Xu, YANG Wensheng. NiFe₂O₄/NiO Nanocomposites as Electrocatalysts for Oxygen Evolution Reaction^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 1999.

Preparation of CeO₂-modified V-NiFeP bifunctional catalyst and its electrolytic performance of seawater

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments