Carboxyl Functionalized Microfiltration Membrane PSF-g-PMAA： Preparation， Rejection and Removal Properties for Triazine Herbicides

doi:10.7503/cjcu20220695

Abstract

Abstract:

A redox surface-initiating system of —NH₂/S₂O $82$ ^- was constituted at the interface of amine-based chloromethylated polysulfone（CMPSF） microfiltration membrane by using persulfate. MAA was graft-polymerized on the surface of microfiltration membrane by using the surface-initiating graft-polymerization method， and the grafted microfiltration membrane of PSF-g-PMAA was obtained. The rejection and removing performance of PSF-g-PMAA membrane for the three triazine herbicides（ametryn， prometryn and atrazine） from water was examined by using isothermal adsorption experiments and the permeation experiments. The experimental results show that PSF-g-PMAA membrane has strong removal properties for the three triazine herbicides under the synergy adsorption of electrostatic interaction and hydrogen bond interaction， and the maximum adsorption capacity of PSF-g-PMAA membrane for ametryn can reach up to 0.18 μmol/cm²（41 μg/cm²）. Using an injection filter with a membrane area of 1.77 cm²， the rejection rate of PSF-g-PMAA membrane for the solutions of the three triazine herbicides with a concentration of 0.8 mg/L can be closed to 100% under 100 mL of penetrating liquids.

Key words: Grafted-microfiltration membrane, Methacrylic acid, Triazine herbicides, Rejection, Removal

CLC Number:

O631.6

TrendMD:

DU Ruikui, GAO Baojiao, MEN Jiying. Carboxyl Functionalized Microfiltration Membrane PSF-g-PMAA： Preparation， Rejection and Removal Properties for Triazine Herbicides[J]. Chem. J. Chinese Universities, 2023, 44(4): 20220695.

Figures/Tables 13

References 22

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Membrane	Herbicide	Rejection rate（%）	Ref.
PSF⁃g⁃PMAA microfiltration membrane	Triazine herbicides	ca. 100	This study
PSF NF membrane	Atrazine	96.5	［20］
Dow NF membrane 270	Prometryn	92	［21］
Dow RO membrane BW30	Atrazine	98	［22］
RO membrane ESPA2	Atrazine	99	［22］

Membrane	Herbicide	Rejection rate（%）	Ref.
PSF⁃g⁃PMAA microfiltration membrane	Triazine herbicides	ca. 100	This study
PSF NF membrane	Atrazine	96.5	［20］
Dow NF membrane 270	Prometryn	92	［21］
Dow RO membrane BW30	Atrazine	98	［22］
RO membrane ESPA2	Atrazine	99	［22］

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