Fiber Supported Carbon Black Metal Phthalocyanine Axial Complex to Mimic Enzyme for Highly Efficient Catalytic Degradation of Organic Pollutant in Water†

doi:10.7503/cjcu20200143

Abstract

Abstract:

Natural heme catalase has high selective catalysis, but it is easy to deactivate. The enzyme-like catalyst carbon black iron hexadecachlorophthalocyanine axial complex(FePcCl₁₆-Py-CB)was synthesized for improving the activity and stability of enzyme. In the catalyst, FePcCl₁₆ with stable performance worked as active site, tetraminopyridine was introduced as ligand, carbon back was employed as carrier. Fiber-supported enzyme mimicking catalyst FePcCl₁₆-Py-CB@LMPET which was easy to separate with water was prepared by FePcCl₁₆-Py-CB loaded on low melting point sheath-core polyester fibers(LMPET) via thermal bonding. The enzyme-like catalytic system was designed based on FePcCl₁₆-Py-CB@LMPET as catalyst, H₂O₂ as oxidant, DXMS as substrate to investigate the catalytic activity and the recycle performance, to explore the catalytic mechanism and the degradation process of DXMS. The results showed that high valent iron oxo[Fe(Ⅳ)=O] produced by heterolytic cleavage of H₂O₂ was the main active species, thus the system exhibited excellent catalytic activity and stable performance under mild condition. The final degradation products of the catalytic system were all small molecular acids within 120 min. The construction of the enzyme-like catalytic system provides a new idea for wastewater treatment.

Key words: Low melting point sheath-core polyester fiber, Carbon black, Metal phthalocyanine, Enzyme-like catalyst, Organic pollutant

CLC Number:

O643

TrendMD:

XIA Yun, Lü Wangyang, CHEN Wenxing, LI Nan. Fiber Supported Carbon Black Metal Phthalocyanine Axial Complex to Mimic Enzyme for Highly Efficient Catalytic Degradation of Organic Pollutant in Water^†[J]. Chem. J. Chinese Universities, 2020, 41(7): 1582.

Figures/Tables 8

References 30

[1]	Abtahi S. M., Marbelia L., Gebreyohannes A. Y., Ahmadiannamini P., Joannis-Cassan C., Albasi C., de Vos W. M., Vankelecom I. F. J., Sep. Purif. Technol., 2019, 209, 470—481
[2]	Liwarska-Bizukojc E., Galamon M., Bernat P., Water Air, Soil Pollut., 2018, 229, 1—11 doi: 10.1007/s11270-017-3647-3 URL
[3]	Zhao F., Repo E., Yin D., Chen L., Kalliola S., Tang J., Iakovleva E., Tam K. C., Sillanpää M., Sci. Rep., 2017, 7, 1—14 doi: 10.1038/s41598-016-0028-x URL pmid: 28127051
[4]	Ghanbari F., Moradi M., Chem. Eng. J., 2017, 310, 41—62
[5]	Wang Z., Du Y., Yang C., Liu X., Zhang J., Li E., Zhang Q., Wang X., Sci. Total Environ., Sci. Total Environ., 2017, 609, 1423—1432 URL pmid: 28800685
[6]	Kumari M., Kumar A., Chemosphere, 2020, 240, 1—11
[7]	Sorokin A. B., Chem. Rev., 2013, 113, 8152—8191
[8]	Hupp J. T., Nat. Chem., 2010, 2, 432—433 URL pmid: 20489705
[9]	De la Torre B., Švec M., Hapala P., Redondo J., Krej$\check{c}$í O., Lo R., Manna D., Sarmah A., Nachtigallová D., Tu$\check{c}$ek J., Błoński P., Otyepka M., Zbo$\check{r}$il R., Hobza P., Jelínek P., Nat. Commol/Lun., 2018, 9, 1—9
[10]	Mani V., Devasenathipathy R., Chen S. M., Gu J. A., Huang S. T., Renew. Energ., 2015, 74, 867—874
[11]	Hu J., Liu H., Wang L., Li N., Xu T., Lu W., Zhu Z., Chen W., Carbon, 2016, 100, 408—416 doi: 10.1016/j.carbon.2016.01.010 URL
[12]	Şenocak A., Demirbaş E., Durmuş M. , 23-Phthalocyanine-nanocarbon Materials and Their Composites: Preparation, Properties, and Applications. In Nanocarbon and Its Composites, Eds.: Khan A. , Jawaid M., Inamuddin, Asiri A. M., Woodhead Publishing, Cambridge, 2019, 677—709
[13]	Wang X., Lu W., Chen Y., Li N., Zhu Z., Wang G., Chen W., Chem. Eng. J., 2018, 335, 82—93
[14]	Zhu Z., Lu W., Li N., Xu T., Chen W., Chem. Eng. J., 2017, 321, 58—66
[15]	Zhu Z., Chen Y., Gu Y., Wu F., Lu W., Xu T., Chen W., Water Res., 2016, 93, 296—305 URL pmid: 26949842
[16]	Zhu M., Chen J., Guo R., Xu J., Fang X., Han Y. F., Appl. Catal. B Environ, 2019, 251, 112—118
[17]	Wang L., Lu W., Ni D., Xu T., Li N., Zhu Z., Chen H., Chen W., Chem. Eng. J., 2017, 330, 625—634
[18]	Huang G., Liu Y., Cai J. L., Chen X. F., Zhao S. K., Guo Y. A., Wei S. J., Li X., Appl. Surf. Sci., 2017, 402, 436—443
[19]	Han X., Han Z., Li J., Zhao J., Zhao X., J. Colloid Interface Sci., 2019, 533, 333—343 URL pmid: 30172144
[20]	Cao R., Thapa R., Kim H., Xu X., Gyu Kim M., Li Q., Park N., Liu M., Cho J., Nat. Commol/Lun., 2013, 4, 1—7
[21]	Mphuthi N. G., Adekunle A. S., Fayemi O. E., Olasunkanmi L. O., Ebenso E. E., Sci. Rep., 2017, 7, 1—20 URL pmid: 28127051
[22]	Lu W., Li N., Bao S., Chen W., Yao Y., Carbon, 2011, 49, 1699—1709 doi: 10.1016/j.carbon.2010.12.055 URL
[23]	Liu H., Bao S., Cai Z., Xu T., Li N., Wang L., Chen H., Lu W., Chen W., Chem. Eng. J., 2017, 317, 1092—1098 doi: 10.1016/j.cej.2017.01.086 URL
[24]	Li N., Wang Y., Wu C., Lu W., Pei K., Chen W., Appl. Surf. Sci., 2018, 434, 1112—1121 doi: 10.1016/j.apsusc.2017.11.048 URL
[25]	Chen Y., Lu W., Wang X., Chen W., Appl. Surf. Sci., 2018, 453, 110—119 doi: 10.1016/j.apsusc.2018.04.188 URL
[26]	Ju L., Li Z., Xu S., Li Q., Fullerenes, Nanotubes and Carbon Nanostructures, 2017, 25, 335—341 doi: 10.1080/1536383X.2017.1292255 URL
[27]	Dong L., Xu T., Chen W., Lu W., Chem. Eng. J., 2019, 357, 198—208 doi: 10.1016/j.cej.2018.09.094 URL
[28]	Lee J. M., Kim S. J., Kim J. W., Kang P. H., Nho Y. C., Lee Y. S., J. Indus. Engin. Chem., 2009, 15, 66—71 doi: 10.1016/j.jiec.2008.08.010 URL
[29]	Balaji M., Nithya P., Kasirajan K., Alexpandi R., Mayakrishnan A., Palanisamy S., Jegatheeswaran S., Selvam S., Ravi A. V., Karunakaran M., Cai Y., Sundrarajan M., Mater. Sci. Engin. C, 2020, 1—20
[30]	Guo Z., Guo A., Guo Q., Rui M., Zhao Y., Zhang H., Zhu S., Chem. Eng. J., 2017, 307, 722—728 doi: 10.1016/j.cej.2016.08.138 URL