Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (11): 2572.doi: 10.7503/cjcu20180236
• Polymer Chemistry • Previous Articles Next Articles
LIN Musong1, PENG Lei1,*(), FU Qiang1, QIAN Yihua1, CHEN Tiansheng1, ZHANG Sheng2, MA Xiaoqian3
Received:
2018-03-28
Online:
2018-11-10
Published:
2018-10-09
Contact:
PENG Lei
E-mail:penglei1025@whu.edu.cn
Supported by:
CLC Number:
TrendMD:
LIN Musong, PENG Lei, FU Qiang, QIAN Yihua, CHEN Tiansheng, ZHANG Sheng, MA Xiaoqian. Research on Self-healing Insulating Material Based on Host-guest Cooperation†[J]. Chem. J. Chinese Universities, 2018, 39(11): 2572.
Sample | V(HEMA)/mL | V(BA)/mL | m(PVP)/g | m(HEMA-Ad)/g | m(CD-Al2O3 NPs)/g | V(EGDMA)/μL |
---|---|---|---|---|---|---|
1 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 0 |
2 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 0.5 |
3 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 1 |
4 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 2 |
Ref.[1] | 0.5 | 2.37 | 0.66 | 0.6 | 0 | 1 |
Ref.[2] | 0.5 | 2.37 | 0 | 0.6 | 0.3 | 1 |
Table 1 Composition of samples for synthesis of PVP/p(CHEMA-co-BA)
Sample | V(HEMA)/mL | V(BA)/mL | m(PVP)/g | m(HEMA-Ad)/g | m(CD-Al2O3 NPs)/g | V(EGDMA)/μL |
---|---|---|---|---|---|---|
1 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 0 |
2 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 0.5 |
3 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 1 |
4 | 0.5 | 2.37 | 0.66 | 0.6 | 0.3 | 2 |
Ref.[1] | 0.5 | 2.37 | 0.66 | 0.6 | 0 | 1 |
Ref.[2] | 0.5 | 2.37 | 0 | 0.6 | 0.3 | 1 |
Sample | Storage modulus/MPa | Tg/℃ | ||||
---|---|---|---|---|---|---|
20 ℃ | 50 ℃ | 90 ℃ | E'20 ℃/E'50 ℃ | E'50 ℃/E'90 ℃ | ||
2 | 300.8 | 48.83 | 1.127 | 6.16 | 43.32 | 78.1 |
3 | 399.0 | 79.13 | 2.313 | 5.04 | 34.21 | 81.3 |
4 | 432.3 | 64.78 | 1.030 | 6.67 | 62.08 | 95.8 |
Table 2 Dynamic thermo-mechanical analysis of PVP/p(HEMA-co-BA)
Sample | Storage modulus/MPa | Tg/℃ | ||||
---|---|---|---|---|---|---|
20 ℃ | 50 ℃ | 90 ℃ | E'20 ℃/E'50 ℃ | E'50 ℃/E'90 ℃ | ||
2 | 300.8 | 48.83 | 1.127 | 6.16 | 43.32 | 78.1 |
3 | 399.0 | 79.13 | 2.313 | 5.04 | 34.21 | 81.3 |
4 | 432.3 | 64.78 | 1.030 | 6.67 | 62.08 | 95.8 |
Condition | Volume resistivity/ (Ω·m) | Surface resistivity/Ω | Relative permittivity | AC electrical strength (inoil)/(MV·m-1) | DC electrical strength (in oil)/(MV·m-1) |
---|---|---|---|---|---|
Normal | 3.2×107 | 7.2×1010[ | 21.7 | 12.5[ | 14.7[ |
Drying for 2h at 50 ℃, vacuum | 4.1×108 | 3.5×1010[ | 18.7 |
Table 3 Insulating properties of PVP/p(HEMA-co-BA)
Condition | Volume resistivity/ (Ω·m) | Surface resistivity/Ω | Relative permittivity | AC electrical strength (inoil)/(MV·m-1) | DC electrical strength (in oil)/(MV·m-1) |
---|---|---|---|---|---|
Normal | 3.2×107 | 7.2×1010[ | 21.7 | 12.5[ | 14.7[ |
Drying for 2h at 50 ℃, vacuum | 4.1×108 | 3.5×1010[ | 18.7 |
Sample | EY/MPa | ε/(%) | σ/MPa | Self-healing efficiency, η(%) | ||
---|---|---|---|---|---|---|
Before self-healing | After self-healing | Before self-healing | After self-healing | |||
1 | 0.36 | 337.65 | 225.33 | 0.612 | 0.519 | 85.2 |
2 | 7.64 | 173.33 | 24.76 | 0.812 | 0.586 | 72.2 |
3 | 9.42 | 161.39 | 70.66 | 1.452 | 0.987 | 67.98 |
4 | 15.00 | 98.41 | 29.11 | 2.036 | 1.341 | 65.89 |
Ref.[1] | 9.14 | 158.35 | 0 | 1.431 | 0 | 0 |
Ref.[2] | 8.53 | 150.23 | 40.37 | 1.128 | 0.413 | 36.61 |
Table 4 Mechanical properties and self-healing efficiency of PVP/p(HEMA-co-BA)
Sample | EY/MPa | ε/(%) | σ/MPa | Self-healing efficiency, η(%) | ||
---|---|---|---|---|---|---|
Before self-healing | After self-healing | Before self-healing | After self-healing | |||
1 | 0.36 | 337.65 | 225.33 | 0.612 | 0.519 | 85.2 |
2 | 7.64 | 173.33 | 24.76 | 0.812 | 0.586 | 72.2 |
3 | 9.42 | 161.39 | 70.66 | 1.452 | 0.987 | 67.98 |
4 | 15.00 | 98.41 | 29.11 | 2.036 | 1.341 | 65.89 |
Ref.[1] | 9.14 | 158.35 | 0 | 1.431 | 0 | 0 |
Ref.[2] | 8.53 | 150.23 | 40.37 | 1.128 | 0.413 | 36.61 |
Fig.11 Samples without CD-Al2O3 NPs(A), without PVP(B) and self-healing test of PVP/p(HEMA-co-BA) after smearing cyclodextrin solution at cutting surface(C)
[1] | Jiao Z., Xia Q., Electric Power Supply, 2011, 28(2), 64—66 |
(焦振, 夏泉. 供用电, 2011, 28(2), 64—66) | |
[2] | Zhang D. G., Cable Fault Analysis and Test, China Electric Power Press, Beijing, 2005 |
(张栋国, 北京:中国电力出版社, 2005) | |
[3] | Zhou Y., Research on Factors Influencing Cable Insulation Performance and Its Countermeasures,, Dalian University of Technology, Dalian, 2015 |
(周阳. 影响电缆绝缘性能的因素研究及其对策, 大连: 大连理工大学, 2015) | |
[4] | Xiong B. F., Tang C., Wang Q., Zhu S. P., Li X., Zhang S., Journal of Southwest China Normal University(Natural Science), 2016, 41(8), 138—144 |
(熊必凤, 唐超, 王谦, 祝诗平, 李旭, 张松. 西南师范大学学报(自然科学版), 2016, 41(8), 138—144) | |
[5] | Mynar J. L., Aida T., Nature, 2008, 451(7181), 895—896 |
[6] | Chen T., Chen R., Zhong J., Liu J., Journal of Materials Chemistry A, 2015, 3(18), 9510—9516 |
[7] | Zhang H., Wang P., Yang J., Composites Science & Technology, 2014, 94(4), 23—29. |
[8] | Na X. M., Gao F., Zhang L. Y., Su Z. G., Ma G. H., ACS Macro Letters, 2016, 1(6), 697—700 |
[9] | Rule J., Brown E., Sottos N., White S., Moore J., Advanced Materials, 2010, 17(2), 205—208 |
[10] | Qiao L., Xue Y., Zhang Q., Journal of Materials Science, 2017, 53(2), 1—14 |
[11] | Gergely R. C. R., Cruz W. A. S., Krull B. P., Pruitt E. L., Wang J., Sottos N. R., White S. R., Advanced Functional Materials, 2018, (28), 1704197 |
[12] | Postiglione G., Alberini M., Leigh S., Levi M., Turri S., ACS Applied Materials & Interfaces, 2017, 9(16), 14371—14378 |
[13] | He Y., Liao S., Jia H., Cao Y., Wang Z., Wang Y., Advanced Materials, 2015, 27(31), 4622—4627 |
[14] | Ling J., Rong M. Z., Zhang M. Q., Journal of Materials Chemistry, 2011, 21(45), 18373—18380 |
[15] | Wang S., Zhang Z., Chen B., Shao J., Guo Z., Journal of Applied Polymer Science,2018, 135(17), 46143(1—8) |
[16] | Herbst F., Binder W. H., Self-Healing Polymers via Supramolecular, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2013, 273—300 |
[17] | Luan Y. G., Zhang X. A., Jiang S. L., Chen J. H., Lyu Y. F., Chinese Journal of Polymer Science, 2018, 36(5), 584—591 |
[18] | Burattini S., Colquhoun H. M., Fox J. D., Friedmann D., Greenland B. W., Harris P. J. F., Hayes W., Mackayc M. E., Rowan S. J., Chemical Communications, 2009, 6717—6719 |
[19] | Mozhdehi D., Ayala S., Cromwell O. R., Guan Z., Journal of the American Chemical Society, 2014, 136(46), 16128—16131 |
[20] | Nakahata M., Takashima Y., Yamaguchi H., Harada A., Nature Communications, 2011, 2(1), 511—517 |
[21] | Zhang M., Xu D., Yan X., Chen J., Dong S., Zheng B., Huang F., Angewandte Chemie, 2012, 124(28), 7117—7121 |
[22] | Wang Q., Mynar J. L., Yoshida M., Yoshida M., Lee E., Lee M., Okuro K., Kinbara K., Aida T., Nature, 2010, 463(7279), 339—343 |
[23] | Zhang D. L., Ju X., Li L. H., Kang Y., Gong X. L., Li B. J., Zhang S., Chemical Communications, 2015, 51(29), 6377—6380 |
[24] | Hoogenboom R., Angewandte Chemie International Edition, 2012, 51(48), 11942—11944 |
[25] | Wietor J. L., Sijbesma R. P., Angewandte Chemie International Edition, 2008, 47(43), 8161—8163 |
[26] | Cordier P., Tournilhac F., SouliéZiakovic C., Leibler L., Nature, 2008, 451(7181), 977—980 |
[27] | Wang R. Y., Design, Synthesis and Properties of Novel Functional Compounds Containing Squaraines, Fuzhou University, Fuzhou, 2010 |
(王如勇. 新型含方酸菁单体功能化合物的设计、 合成与性质研究, 福州: 福州大学, 2010) | |
[28] | Wu Y., Zuo F., Zheng Z., Ding X., Peng Y., Nanoscale Research Letters, 2009, 4(7), 738—747 |
[29] | Luo C .Y., Electrical Manufacturing, 2006, (1), 63—64 |
(罗传勇. 电气制造, 2006, (1), 63—64) | |
[30] | General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of the People's Republic of China GB/T 1692-2008, Vulcanized Rubber-Determination of Insulation Resistivity, Standards Press of China, Beijing |
(中华人民共和国国家质量监督检验检总局, 中国国家标准化管理委员会GB/T 1692-2008, 硫化橡胶绝缘电阻率的测定, 北京: 中国标准出版社) | |
[31] | General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of the People's Republic of China, GB/T 1408.1-2006, Test Methods for the Electrical Strength of Insulating Materials, Part 1: Under Frequency Test, Standards Press of China, Beijing |
(中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会, GB/T 1408.1-2006 , 绝缘材料电气强度试验方法第1部分: 工频下试验, 北京: 中国标准出版社) | |
[32] | General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China, Standardization Administration of the People's Republic of China, GB/T 1408.2-2006, Test Methods for the Electrical Strength of Insulating Materials, Part 2: Application of DC Voltage Test, Standards Press of China, Beijing |
(中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会, GB/T 1408.2-2006, 绝缘材料电气强度试验方法第2部分: 对应用直流电压试, 北京: 中国标准出版社) |
[1] | ZHOU Yonghui, LI Yao, WU Yuxuan, TIAN Jing, XU Longquan, FEI Xu. Synthesis of A Novel Photoluminescence Self-healing Hydrogel [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210606. |
[2] | GAO Huiling, CAO Zhenzhen, GU Fang, WANG Haijun. Monte Carlo Simulation on Self-healing Behaviour of Hydrogen-bonded Hydrogel [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220482. |
[3] | LI Zhanfeng, LIU Benxue, LIU Xiaochan, WANG Xinqiang, ZHANG Jing, YU Shimo, ZHAO Xinfu, ZHANG Xin’en, YI Xibin. Mechanism of the Removal of Acetylacetone Ligands in Zirconia Wet Gel and Fabrication of Zirconia Aerogel Composites [J]. Chem. J. Chinese Universities, 2021, 42(9): 2904. |
[4] | WANG Linlin, LI Lei, FENG Shengyu. Research Progress of Silicone Supramolecular Materials [J]. Chem. J. Chinese Universities, 2021, 42(7): 2111. |
[5] | GUO Wenjin, WANG Xiaohan, LI Xiang, LI Yang, SUN Junqi. Reprocessable and Self-healing Polybutadiene Rubber Based on Metal Coordination [J]. Chem. J. Chinese Universities, 2020, 41(9): 2090. |
[6] | SHENG Yeming,CHENG Bo,LU Xun. Research on Self-healing Polypolyurethane Elastomer Based on Multiple Reversible Action [J]. Chem. J. Chinese Universities, 2020, 41(3): 572. |
[7] | LIN Musong, PENG Lei, ZHANG Sheng, LI Li, FU Qiang, HOU Junbo. Preparation and Functions of Self-healing Light-shielding Paints for Cable Cover [J]. Chem. J. Chinese Universities, 2019, 40(8): 1766. |
[8] | LI Lan,QIAN Yong,YANG Dongjie,QIU Xueqing. Preparation of Lignin/silica Nanoparticle Based Microcapsules and Their Application in Self-healing Coatings† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1293. |
[9] | Enshuang ZHANG,Hongyan HUANG,Tao LIU,Lijuan HE,Hui GUO,Wenjing LI,Fan ZHANG,Jieying YANG,Hao ZHANG,Yingmin ZHAO. Synthesis and Reusable Properties of Robust Al2O3-SiO2 Aerogel [J]. Chem. J. Chinese Universities, 2019, 40(12): 2566. |
[10] | GAO Feilong, LI Yongcun, LUAN Yunbo, XUE Zhicheng, GUO Zhangxin, ZHANG Qi, WU Guiying. Enhancement Mechanisms of Mechanical and Self-Healing Properties of Thermoplastic Polyurethane Composites Induced by Different G-CNT Hybridization Systems† [J]. Chem. J. Chinese Universities, 2018, 39(4): 832. |
[11] | LIU Hongwan, WEI Fang, WAN Li, GU Fang, WANG Haijun. Monte Carlo Simulation on the Self-healing of Dynamic Bond-based Gel† [J]. Chem. J. Chinese Universities, 2018, 39(2): 367. |
[12] | XU Xiaojian, GUO Jianwei, ZHU Dongyu, ZHONG Xing. Synthesis of Symmetrical Disubstituted Bridgehead Adamantane Derivatives† [J]. Chem. J. Chinese Universities, 2014, 35(8): 1686. |
[13] | ZHANG Tao, DONG Xue, ZHANG Zongtao. Surface Modification of Microporous and Mesoporous Molecular Sieves and Their Super Insulation Properties† [J]. Chem. J. Chinese Universities, 2014, 35(4): 689. |
[14] | Gu Fang-zhi, Wang Jian-ji. Enumeration of Isomers of Substituted Adamantane [J]. Chem. J. Chinese Universities, 1991, 12(5): 677. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||