Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (4): 689.doi: 10.7503/cjcu20140096
• Articles: Inorganic Chemistry • Previous Articles Next Articles
ZHANG Tao, DONG Xue, ZHANG Zongtao*()
Received:
2014-01-29
Online:
2014-04-10
Published:
2014-03-11
Contact:
ZHANG Zongtao
E-mail:zzhang@jlu.edu.cn
Supported by:
CLC Number:
TrendMD:
ZHANG Tao, DONG Xue, ZHANG Zongtao. Surface Modification of Microporous and Mesoporous Molecular Sieves and Their Super Insulation Properties†[J]. Chem. J. Chinese Universities, 2014, 35(4): 689.
Sample | Pore size/nm | SBET/(m2·g-1) | VBJH/(cm3·g-1) | Pore type | n(Si)/n(Al) |
---|---|---|---|---|---|
SBA-15 | 7.56 | 790 | 1.08 | Meso | ∞ |
MCM-41 | 2.48 | 904 | 0.84 | Meso | ∞ |
MAS-5 | 2.70 | 1150 | 1.17 | Micro & Meso | 30 |
ZSM-5 | 0.55 | 440 | 0.16 | Micro | 30 |
Silica aerogel[ | 2—5 | 600—1000 | Meso | ∞ |
Table 1 Properties of as-synthesized materials
Sample | Pore size/nm | SBET/(m2·g-1) | VBJH/(cm3·g-1) | Pore type | n(Si)/n(Al) |
---|---|---|---|---|---|
SBA-15 | 7.56 | 790 | 1.08 | Meso | ∞ |
MCM-41 | 2.48 | 904 | 0.84 | Meso | ∞ |
MAS-5 | 2.70 | 1150 | 1.17 | Micro & Meso | 30 |
ZSM-5 | 0.55 | 440 | 0.16 | Micro | 30 |
Silica aerogel[ | 2—5 | 600—1000 | Meso | ∞ |
Sample | Density*/ (g·cm-3) | Thermal conductivity/ (W·m-1·K-1) |
---|---|---|
SBA-15 | 0.623 | 0.040 |
MCM-41 | 0.652 | 0.038 |
MAS-5 | 0.612 | 0.035 |
SBA-15-P | 0.642 | 0.035 |
MCM-41-P | 0.680 | 0.028 |
MAS-5-P | 0.674 | 0.017 |
ZSM-5 | 0.745 | 0.022 |
Silica aerogels[ | 0.003—0.35 | 0.020 |
Table 2 Thermal conductivity of as-synthesized thermal insulation materials
Sample | Density*/ (g·cm-3) | Thermal conductivity/ (W·m-1·K-1) |
---|---|---|
SBA-15 | 0.623 | 0.040 |
MCM-41 | 0.652 | 0.038 |
MAS-5 | 0.612 | 0.035 |
SBA-15-P | 0.642 | 0.035 |
MCM-41-P | 0.680 | 0.028 |
MAS-5-P | 0.674 | 0.017 |
ZSM-5 | 0.745 | 0.022 |
Silica aerogels[ | 0.003—0.35 | 0.020 |
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