Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (12): 2125.doi: 10.7503/cjcu20160608
• Articles: Inorganic Chemistry • Previous Articles Next Articles
YANG Shuang, JI Xiaohui, YANG Wensheng*()
Received:
2016-08-29
Online:
2016-12-10
Published:
2016-11-18
Contact:
YANG Wensheng
E-mail:wsyang@jlu.edu.cn
Supported by:
CLC Number:
TrendMD:
YANG Shuang, JI Xiaohui, YANG Wensheng. Mechanism in the Preparation of Gold Nanoflowers by Ascorbic Acid Reduction†[J]. Chem. J. Chinese Universities, 2016, 37(12): 2125.
Fig.1 UV-Vis spectra(A) and corresponding TEM images(B—F) of gold nanoparticles obtained under different concentrations of AAConcentration of AA/(mmol·L-1): (A) a. 0; b. 0.75; c. 1.25; d. 1.75; e. 2.50; f. 5.00. (B) 0; (C) 0.75; (D) 1.25; (E) 1.75; (F) 5.00. Inset of (F): high-resolution TEM images of a branch of the gold nanoflowers. All the data were collected after 10 s of the reactions when color of the solutions kept unchanged.
Fig.2 Temporal evolution of the maximum extinction(A) and position of the plasmon bands(B) in UV-Vis spectra under AA concentrations of 0.75 mmol/L(a) and 1.75 mmol/L(b)
Fig.3 Variation in pH values of the reaction solutions with AA concentrations(A), temporal evolution of the maximum extinction(B) and position of the plasmon bands(C) in UV-Vis spectra with AA concentrations of 0.75 mmol/L(a) and 1.75 mmol/L(b) at pH=5.1 and variation in zeta-potential of the 25 nm gold seeds with the AA concentration at pH=5.1(D)
Fig.4 UV-Vis spectra of the gold nanoflowers prepared under different pH values at AA concentration of 1.75 mmol/L(A), TEM images of the as-prepared gold nanoflowers under pH=3.1(B), 5.1(C) and 6.0(D) at AA concentration of 1.75 mmol/LpH: a. 3.1; b. 4.0; c. 5.1; d. 6.0; e. 7.0.
Fig.5 SERS spectra of R6G(10-4 mol/L) in presence of the gold nanoparticles as prepared(A) and the gold nanoflowers synthesized under pH=7.0(λmax=660 nm) capped by CTAB, PVP, citrate and AA(B)(A) a. Gold nanospheres; b. gold nanoflowers prepared under pH=3.1; c. gold nanoflowers prepared under pH=5.1; d. gold nanoflowers prepared under pH=7.0. (B) a. Capped by CTAB; b. capped by PVP; c. capped by citrate; d. capped by AA.
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