Chem. J. Chinese Universities ›› 2017, Vol. 38 ›› Issue (1): 94.doi: 10.7503/cjcu20160476
• Physical Chemistry • Previous Articles Next Articles
LIU Qiongjun, LIN Bizhou*(), LI Peipei, GAO Bifen, CHEN Yilin
Received:
2016-07-05
Online:
2017-01-10
Published:
2016-12-15
Contact:
LIN Bizhou
E-mail:bzlin@hqu.edu.cn
Supported by:
CLC Number:
TrendMD:
LIU Qiongjun, LIN Bizhou, LI Peipei, GAO Bifen, CHEN Yilin. Preparation of BiPO4/BiVO4 Composites with High Visible-light Photocatalytic Activity†[J]. Chem. J. Chinese Universities, 2017, 38(1): 94.
Sample | Molar ratio of BiPO4 to BiVO4 | SBET/(m2·g-1) | Band gap energy/eV |
---|---|---|---|
BiVO4 | 5.6 | 2.36 | |
P1 | 1:10 | 5.7 | 2.36 |
P2 | 2:10 | 5.2 | 2.34 |
P3 | 3:10 | 5.5 | 2.35 |
P4 | 4:10 | 5.7 | 2.35 |
P5 | 5:10 | 5.4 | 2.34 |
Table 1 Molar ratio of BiPO4 to BiVO4, specific surface areas(SBET) and band gap energies of the as-synthesized composites
Sample | Molar ratio of BiPO4 to BiVO4 | SBET/(m2·g-1) | Band gap energy/eV |
---|---|---|---|
BiVO4 | 5.6 | 2.36 | |
P1 | 1:10 | 5.7 | 2.36 |
P2 | 2:10 | 5.2 | 2.34 |
P3 | 3:10 | 5.5 | 2.35 |
P4 | 4:10 | 5.7 | 2.35 |
P5 | 5:10 | 5.4 | 2.34 |
Sample | B | B | P2p | O1s | ||
---|---|---|---|---|---|---|
BiVO4 | 164.1 | 158.7 | 519.2 | 517.2 | 532.4, 530.4 | |
BiPO4 | 164.1 | 158.7 | 132.6 | 532.2, 530.2 | ||
P3 | 165.1 | 159.7 | 517.7 | 516.0 | 132.2 | 531.2, 529.5 |
Table 2 Binding energies(eV) of related elements in samples
Sample | B | B | P2p | O1s | ||
---|---|---|---|---|---|---|
BiVO4 | 164.1 | 158.7 | 519.2 | 517.2 | 532.4, 530.4 | |
BiPO4 | 164.1 | 158.7 | 132.6 | 532.2, 530.2 | ||
P3 | 165.1 | 159.7 | 517.7 | 516.0 | 132.2 | 531.2, 529.5 |
Fig.7 Photocatalytic degradation efficiency of RhB over different photocatalysts under visible-light irradiation(A) and cycling runs of P3(B) with initial concentration of RhB of 5 mg/L and catalyst loading of 0.5 g/L a. Blank; b. BiVO4; c. P1; d. P2; e. P3; f. P4; g. P5; h. O2-purged P3.
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