Extraction Interfacial Properties of La3+ from HNO3 System with TODGA†

doi:10.7503/cjcu20160037

Abstract

Abstract:

The interfacial properties of La³⁺/HNO₃/N,N,N',N'-tetraoctyl diglycolamide(TODGA)/dilute system were studied by the drop volume method, including the effect of TODGA concentration, equilibrium time, types of diluents, La³⁺ concentration system temperature, ionic strength and acidity on the interfacial properties. It was found that: (1) the interfacial saturated adsorption time is about 120 s in this system; (2) the interfacial tension are different with the different TODGA concentrations, so the interfacial saturated adsorption species may exist differences; (3) the decrease of the interfacial tension is bigger in small polarity dilute system, such as octane>cyclohexane>benzene>toluene; (4) because of the protonation effect for TODGA, the interfacial activity enhanced with the increasing of HNO₃ concentration, and reduced the interfacial tension; the presence of NaNO₃ reduced the concentration of free TODGA molecules at the interface, and let the interface tension increased.

Key words: N,N,N'-N'-tetraoctyl diglycolamide(TODGA), La³⁺, Drop volume method, Interfacial property, Extraction

CLC Number:

O647.11

TrendMD:

WEI Bing, CUI Yu, MA Shoutao, YANG Quanning, SUN Guoxin. Extraction Interfacial Properties of La³⁺ from HNO₃ System with TODGA^†[J]. Chem. J. Chinese Universities, 2016, 37(9): 1716.

Figures/Tables 9

Fig.1 Schematic diagram of drop volume device a. Drop volume tube; b. sample tube; c. rubber plug with a groove; d. sample tube rack; e. glass thermostatic water bath; f. injection line; g. syringe; h. trace injection pump; i. retort stand

Fig.2 Effect of droplet formation time on the interfacial tension c L a 3 + =1×10-3 mol/L; c HN O 3 =1 mol/L; c NaN O 3 =1 mol/L; T=298 K. c(TODGA)/(mol·L-1): a. 0; b. 0.01; c. 0.05; d. 0.10; e. 0.15; f. 0.20.

Fig.3 Effect of TODGA concentration on the interfacial tension c L a 3 + =1×10-3 mol/L; c HN O 3 =1 mol/L; c NaN O 3 =1 mol/L; T=298 K; t=150 s.

Fig.4 Effect of La3+ concentration on the interfacial tension cTODGA=0.1 mol/L; c HN O 3 =1 mol/L; c NaN O 3 =1 mol/L; T=298 K, t=150 s.

Fig.5 Effect of La3+ concentration on the distribution ratio

Fig.6 Effect of extractant concentration on the interfacial tension with different types of diluents c L a 3 + =1×10-3 mol/L; c HN O 3 =1 mol/L; c NaN O 3 =1 mol/L; T=298 K; t=150 s. a. TODGA/octane; b. TODGA/cyclohexane; c. TODGA/benzene;d. TODGA/toluene.

Fig.7 Effect of temperature on the interfacial tension c L a 3 + =1×10-3 mol/L; c HN O 3 =1 mol/L; c NaN O 3 =1 mol/L; t=150 s. (A) a. Octane; b. 0.01 mol/L TODGA/octane.(B) a. Benzene; b. 0.1 mol/L TODGA/benzene.

Fig.8 Effect of HNO3 concentration on the interfacial tension with 0.1 mol/L TODGA/octane c L a 3 + =1×10-3 mol/L; c NaN O 3 =1 mol/L; T=298 K; t=150 s.

Fig.9 Effect of NaNO3 concentration on the interfacial tension with 0.1 mol/L TODGA/octane c L a 3 + =1×10-3 mol/L; c HN O 3 =1 mol/L; T=298 K; t=150 s.

References 28

[1]	Chen L., Li Y., Wang Z. W., Peng Z. Y., Yang Z. M., Yuan L. H., Feng W., Chem. J. Chinese Universities,2015, 36(8), 1485—1490
	(陈龙, 李艳, 王真文, 彭智勇, 杨泽明, 袁立华, 冯文. 高等学校化学学报,2015, 36(8), 1485—1490)
[2]	Dutta S., Mohapatra P. K., Manchanda V. K., Appl. Radiat. Isot., 2011, 69, 158—162
[3]	Huang S., Ding S. D., Jin Y. D., Ma L. J., Xia C. Q., Li S. J., Wu Y. X., Huang H., Chem. J. Chinese Universities,2014, 35(7), 1369—1378
	(黄松, 丁松东, 金永东, 马利建, 夏传琴, 李首建, 吴宇轩, 黄璜. 高等学校化学学报,2014, 35(7), 1369—1378)
[4]	Zhu W. B., Ye G. A., Li F. F., Li H. R., J. Radioanal. Nucl. Chem., 2013, 298, 1749—1755
[5]	Zhu W. B., Ye G. A., Li F. F., Li H. R., Journal of Nuclear and Radiochemistry ,2013, 35(4), 229—235
	(朱文彬, 叶国安, 李峰峰, 李会蓉. 核化学与放射化学 ,2013, 35(4), 229—235)
[6]	Sun G. X., Yang Y. H., Sun S. X., Shen J. R., Chem. J. Chinese Universities,1995, 16(11), 1677—1679
	(孙国新, 杨永会, 孙思修, 沈静兰. 高等学校化学学报,1995, 16(11), 1677—1679)
[7]	Wu D. B., Xiong Y., Li D. Q., J. Colloid Interface Sci., 2005, 290, 235—240
[8]	Zhang K., Du C. L., Li R. X., Wu D. C., Journal of Sichuan University,2004, 36(2), 58—61
	(张科, 杜宗良, 李瑞霞, 吴大诚. 四川大学学报,2004, 36(2), 58—61)
[9]	Fang Y. W., Wang J. H., Chem. J. Chinese Universities,1996, 17(2), 298—299
	(方奕文, 王镜和. 高等学校化学学报,1996, 17(2), 298—299)
[10]	Joseph D. B., Michael J. N., Raymond R. D., Derek Y. C. C., Rico F. T., J. Colloid Interface Sci., 2015, 454, 226—237
[11]	M. Soledade C S. Santos., Ana Paula Paiva., J. Colloid Interface Sci., 2014, 413, 78—85
[12]	Jiang R., Zhao J. X., You Y., Acta Chim. Sinica,2005, 63(2), 126—130
	(姜蓉, 赵剑曦, 游毅. 化学学报,2005, 63(2), 126—130)
[13]	Guo L. S., Cao P. Y., Journal of Dalian University,1988, 3(6), 41—42
	(郭立山, 曹佩玉. 大连大学学报,1988, 3(6), 41—42)
[14]	Xiong H. J., Li W., Zhang Y. Y., Journal of Wuhan Polytechnic University,2007, 26(3), 42—44
	(熊会军, 李炜, 张誉赢. 武汉工业学院学报,2007, 26(3), 42—44)
[15]	Zhao J. M., Sun X. B., Li W., J. Colloid Interface Sci., 2006, 294, 429—435
[16]	Sun G. X., Liu M., Cui Y., Yuan M. L., Yin S. H., Solvent Extr. Ion Exch., 2010, 28(4), 482—494
[17]	Lando J. L., Oakley H. T., J. Colloid Interfce Sci., 1967, 25(4), 526—530
[18]	Wilkinson M. C., Kidwell R. L., J. Colloid Interfce Sci., 1971, 35(1), 114—119
[19]	Manori J., Thomas L. B., J. Phys. Chem. B., 2009, 113(34), 11662—11671
[20]	Nave S., Molodo G., Madic C., Testard F., Solvent Extr. Ion Exch., 2004, 22(4), 527—551
[21]	Zhang Y. J., Cui. Y., Hu Y. F., Sun G. X., Chin. J. Inorg. Chem., 2010, 26(4), 663—667
	(张艳菊, 崔玉, 胡玉芬, 孙国新. 无机化学学报, 2010, 26(4), 663—667)
[22]	Yang B. H., Uranium ore Processing Technology, Beijing Research Institute of Chemical Engineering and Metallurgy, Beijing, 2002, 352
	(杨伯和. 铀矿加工工艺学, 北京: 核工业北京化工冶金研究院, 2002, 352)
[23]	Liu J. J., Wang W. W., Li D. Q., Colloids Surf. A: Physicochem. Eng., 2007, 311, 124—130
[24]	Sarikhani K., Jeddi K., Thompson R. B., Park C. B., Chen P., Thermochimica Acta,2015, 609, 1—6
[25]	Zhang Y. J., Cui Y., Liu M., Yin S. H., Sun G. X., Chin. J. Inorg. Chem., 2008, 24(12) , 2047—2050
	(张艳菊, 崔玉, 刘敏, 尹少宏, 孙国新. 无机化学学报, 2008, 24(12) , 2047—2050)
[26]	Gujar R. B., Ansari S. A., Murali M. S., Mohapatra P. K., Manchanda V. K., J. Radioanal. Nucl. Chem., 2010, 284, 377—385
[27]	Zhu W. B., Ye G. A., Li F. F., Jiang D. X., Li H. R., J. Nucl. Radiochem., 2011, 33(6), 328—334
	(朱文彬, 叶国安, 李峰峰, 蒋德祥, 李会蓉. 核化学与放射化学, 2011, 33(6), 328—334)
[28]	Liu X. L., Sun G. X., Cai X. C., Yang X. F., Li Y. X., Sun Z. M., Cui Y., J. Radioanal. Nucl. Chem., 2015, 306, 549—553

Extraction Interfacial Properties of La³⁺ from HNO₃ System with TODGA^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 28

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	TANG Quanjun, LIU Yingxin, MENG Rongwei, ZHANG Ruotian, LING Guowei, ZHANG Chen. Application of Single-atom Catalysis in Marine Energy [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220324.
[2]	BI Gening, XIAO Xiaohua, LI Gongke. Development and Validation of Multiple Physical Fields Coupling Model for Microwave-assisted Extraction [J]. Chem. J. Chinese Universities, 2022, 43(3): 20210739.
[3]	ZHENG Haijiao, JIANG Liyan, JIA Qiong. Arginine Functionalized Magnetic Nanoparticles and Its Application in Phosphopeptides Enrichment [J]. Chem. J. Chinese Universities, 2021, 42(3): 717.
[4]	DENG Jiewei, YANG Yunyun, LIN Li, LUAN Tiangang. Rapid Classification of Daphniamagna and Daphnia pulex by Surface-coated Probe Nanoelectrospray Ionization Mass Spectrometry Lipidomics [J]. Chem. J. Chinese Universities, 2020, 41(9): 2011.
[5]	LI Xiaoqian, ZHANG Hua, LU Haijian, LIU Chang, LIU Qinglong, MA Xiayu, FANG Yuanping, LIANG Dapeng. Mechanism of Photocatalytic Degradation of Rhodamine B by TiO₂ Nanowire Array with Internal Extraction Electrospray Ionization Mass Spectrometry [J]. Chem. J. Chinese Universities, 2020, 41(9): 2003.
[6]	WANG Xiaoru,ZHANG Na,XING Jun. Preparation and Application of Melamine Imprinted Material Using Itaconic Acid as Multidentate Functional Monomer [J]. Chem. J. Chinese Universities, 2020, 41(7): 1521.
[7]	ZHANG Xiaofei, WU Lie, LI Shanshan, ZHU Manyu, CHENG Xiaowei, JIANG Xiu’e. Effect of Phase Behavior of Phospholipids on Lipid Membrane Damage Induced by Graphene Oxide ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 661.
[8]	PIAO Huilan,MA Pinyi,QIN Zucheng,JIANG Yanxiao,SUN Ying,WANG Xinghua,SONG Daqian. Determination of Triazine Herbicides from Fruit Juice Samples Using Effervescence Assisted Microextraction Method Based on Acidic Ionic Liquid Packed Syringe [J]. Chem. J. Chinese Universities, 2020, 41(2): 228.
[9]	WANG Tianqi,YU Qiongwei,FENG Yuqi. Analysis of Imidazole Propionic Acid in Serum of Patients with Type 2 Diabetes Based on NiO@SiO₂ Solid-phase Extraction Coupled with Liquid Chromatography-Mass Spectrometry ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 262.
[10]	CHENG Xiankun, HOU Xue, TIAN Huan, ZHANG Menglong, WEI Hao, ZHAO Zhuo. Synthesis of Macrocyclic Thiacrown Ethers and Their Selective Extraction for Ag(Ⅰ) and Tl(Ⅰ) ^† [J]. Chem. J. Chinese Universities, 2019, 40(9): 1881.
[11]	WU Rong,WANG Huimin,CAO Jun,CHEN Luyao,SU Erzheng. Simultaneous Extraction of Salidroside and Tyrosol from Rhodiolarosea L. Using Tailor-made Deep Eutectic Solvents^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 918.
[12]	ZHANG Lirong,WANG Zhipeng,LIU Ying,XU Chao,CHEN Jing,DING Songdong. Extraction of Trivalent Americium and Europiumfrom Nitric Acid Solution with Di(2-ethylhexyl)dithiophosphinic Acid^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 1.
[13]	MENG Zihui,WANG Yifei,XIE Tengsheng,CHEN Wei,QIU Lili,XUE Min. Molecularly Imprinted Hollow Spheres for the Solid Phase Extraction of Protein^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 62.
[14]	SU Rui,WANG Yihan,CHEN Changbao,SUN Xiuli,LIU Shuying,YANG Hongmei. Determination of Brominated Flame Retardants in Environmental Water by Microwave-assisted Ionic Liquid/ionic Liquid Dispersive Liquid-liquid Microextraction Coupled with DART-Orbitrap Mass Spectrometry^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1934.
[15]	XUE Yun, CAO Meng, YANG Xue, XU Yanlu, YAN Yongde, JI Debin, MA Fuqiu. Electrochemical Extraction of La and Zn-La Alloy Codeposition in Chloride System^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1145.