Fabrication of the Columnar Structure with Gold Nanobowl Arrays Based on Colloidal Lithography†

doi:10.7503/cjcu20130946

Abstract

Abstract:

A novel method was developed to fabricate the structure of a bowl on the top of column on nano/micro scale by selectively etching the photoresist oligomer film using the silica microspheres as masks. The gold nanobowl was formed on the top of the columnar structure as depositing a layor of Au on the surface of sample. By adjusting etching time, the dimension of columnar structure can be controlled. The characteristic transmission band of the material shows a obvious red shift from 500 nm to 760 nm when the height of the columnar structure increases. To investigate the optical property caused by the unique structure and the distribution of electric field around the noble metal, the method of the finite difference time domain was used. The high intensity of electric field was found at the edges and bottom of the gold nanobowl, which is the main influencing factor of the red shift.

Key words: Colloidal crystal, Plasma etching, Photoresist oligomer, Gold nanobowl, Surface plasmon resonance

CLC Number:

TrendMD:

XUE Peihong, WANG Tieqiang, AI Bin, YE Shunsheng, LI Dongfeng, ZHANG Junhu. Fabrication of the Columnar Structure with Gold Nanobowl Arrays Based on Colloidal Lithography^†[J]. Chem. J. Chinese Universities, 2014, 35(5): 1106.

Figures/Tables 5

Fig.1 Preparation of the columnar structure with gold nanobowl arrays

Fig.2 Cross section SEM images of the gold nanobowl on the columnar structure arrays with different etching time^ t/min: (A) 3; (B) 4; (C) 5; (D) 6; (E) 7; (F) 8; (G) 9; (H) 10. (I) the top-view SEM images of the gold nanobowl on the columnar structure arrays(etching time is 10 min).

Fig.3 Plot data of height(a) and diameter(b) of the gold nanobowl on the columnar structure arrays

Fig.4 Transmission spectra of the gold nanobowl on the columnar structure arrays with different etching time^Etching time/min: a. 5; b. 3; c. 6; d. 4; e. 7; f. 8; g. 9; h. 10.

Fig.5 Transmission spectrum(A), transmission spectrum calculated by the FDTD(λ= 675 nm)(B) and distribution of electric field(C) of the gold nanobowl on the columnar structure arrays with 10 min etching

References 23

[1]	Ai B., Yu Y., Möhwald H., Zhang G., Nanotechnology, 2013, 24(2), 035303
[2]	Zhang X.M., Micro/Nanofabrication of Functional Plasmonic Materials, Jilin University, Changchun, 2012
	(张学民. 贵金属光功能纳微米结构的构筑与性能研究, 长春: 吉林大学, 2012)
[3]	Baca A. J., Truong T. T., Cambrea L. R., Montgomery J. M., Gary S. K., Abdula D., Banks T. R., Yao J. M., Nuzzo R. G., Rogers J. A., Appl. Phys. Lett., 2009, 94, 243109
[4]	Daniel M. C., Astruc D., Chem. Rev., 2004, 104, 293—346
[5]	Brolo A. G., Gordon R., Leathem B., Kavanagh K. L., Langmuir, 2004, 20, 4813—4815
[6]	Huang Z. P., Fang H., Zhu J., Adv. Mater., 2007, 19, 744—748
[7]	Liao L., Liu K. H., Wang W. L., Bai X. D., Wang E. G., Liu Y. L., Li J. C., Liu C., J. Am. Chem. Soc., 2007, 129, 9562—9563
[8]	Gao C. B., Zhang Q., Yin Y. D., J. Am. Chem. Soc., 2011, 133, 19706—19709
[9]	Zhang P., Guo Y. Y., J. Am. Chem. Soc., 2009, 131, 3808—3809
[10]	Kastner M. A., Phys. Today, 1993, 46, 24—31
[11]	Reed M. A., Sci. Am., 1993, 268, 118—123
[12]	Li W. Z., Xie S. S., Qian L. X., Chang B. H., Zou B. S., Zhou W. Y., Zhao R. A., Wang G., Science, 1996, 274, 1701—1703
[13]	LiKharev K. K., IBM J. Res. Dev., 1988, 32, 144—158
[14]	Crooks R. M., Zhao M., Sun L., Chechik V., Yeung L. K., Acc. Chem. Res., 2001, 34, 181—190
[15]	Ye J., Verellen N., Van Roy W., Lagae L., Maes G., Borghs G., Van Dorpe P., ACS Nano, 2010, 4(3), 1457—1464
[16]	Van D. P., Ye J., ACS Nano, 2011, 5(9), 6774—6778
[17]	Ye J., Van Dorpe P., Van Roy W., Borghs G., Maes G., Langmuir, 2009, 25(3), 1822—1827
[18]	Rao Y. Y., Tao Q., An M., Rong C., Dong J., Dai Y., Qian W. P., Langmuir, 2011, 27, 13308—13313
[19]	Li Y., Cai W. P., Duan G. T., Chem. Mater., 2008, 20(3), 615—624
[20]	Chen L., Liu F. X., Wang Z. L., Chin. Phys. Lett., 2011, 28(5), 057801
[21]	Yu Y., Gan L., Zhang G., Yang B., Colloids and Surfaces A, Physicochem. Eng. Aspects, 2012, 405, 51—58
[22]	Stöber W., Fink A., J. Colloid. Interface. Sci., 1968, 26, 62—69
[23]	Yan X., Yao J. M., Lu G., Li X., Zhang J., Han K., Yang B., J. Am. Chem. Soc., 2005, 127, 7688—7689

Related Articles 15

[1]	GE Haoying, DU Jianjun, LONG Saran, SUN Wen, FAN Jiangli, PENG Xiaojun. Surface Functionalized Gold Nanomaterials in Tumor Diagnosis and Treatment [J]. Chem. J. Chinese Universities, 2021, 42(4): 1202.
[2]	WANG Yawen, LI Dong, LIANG Wenkai, SUN Yinghui, JIANG Lin. Multiplex Structures of Plasmonic Metal Nanoparticles and Their Applications [J]. Chem. J. Chinese Universities, 2021, 42(4): 1213.
[3]	ZHANG Aiqin, WANG Man, SHEN Gangyi, JIN Jun. Interactions Between Polybrominated Diphenyl Ethers and Human Serum Albumin Using SPR and Molecular Docking [J]. Chem. J. Chinese Universities, 2020, 41(9): 2054.
[4]	LI Dong,SUN Yinghui,WANG Zhongshun,HUANG Jing,Lü Nan,JIANG Lin. Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 221.
[5]	SUN Weixin, LIU Jia, WANG Jiazheng, ZHANG Yimiao, JIN Lei, ZHOU Jianzhang, YANG Fangzu, WU Deyin, TIAN Zhongqun. Preparation of Platinum-modified Uniform Gold Nanopillar Electrodes and Photoelectrocatalytic Oxidation of Methanol [J]. Chem. J. Chinese Universities, 2020, 41(12): 2788.
[6]	WU Dan, LI Man, ZHONG Yao, AN Kuisheng, CHEN Yanwei. Property of Au Nanoshuttles with Arrow-head Prepared via Wet Chemical Synthetic Method^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1617.
[7]	LI Kaifeng,WU Dan,CHEN Yanwei. Effect of Copper Doping on the Growth and Optical Properties of Au Nanorods^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 855.
[8]	DENG Caisong, PAN Tingting, DU Lan, WANG Ming, NI Haibin, NI Xiaoqi. Fabrication of Monolayer Crystalline Films on Optical Fiber End by Micro-flow Injection Method^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 708.
[9]	HE Xiaoqin, HE Junlin, XU Hua, GUO Lei, XIE Jianwei. Active Conformation of DNA Aptamer Against Recombinant Human Erythropoietin-α^† [J]. Chem. J. Chinese Universities, 2018, 39(1): 48.
[10]	HAN Linhuan, LI Kaifeng, CHEN Yanwei. Growth of Gold Nanorods and Their Interaction with Ferric Chloride^† [J]. Chem. J. Chinese Universities, 2017, 38(5): 706.
[11]	GONG Xiaoqing, WAN Xiumei, LU Danfeng, GAO Ran, CHENG Jin, QI Zhimei. Studies of Electrochemical Polymerization of Thionine Using a Wavelength-interrogated Surface Plasmon Resonance Sensor^† [J]. Chem. J. Chinese Universities, 2017, 38(4): 567.
[12]	SHI Wen, SHAN Guiye, CHEN Yanwei. Surface Modification of Au Nanorods and Their Interaction with H₂ $O 2 †$ [J]. Chem. J. Chinese Universities, 2017, 38(4): 517.
[13]	TENG Xiaobo,ZHANG Chunxia,ZHANG Ying. Synthesis of the Supported Au Polystyrene/poly(acrylic acid) Composite Microspheres and Their pH Regulated Performance^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1509.
[14]	ZHANG Lingyue, CHI Yanan, SHAN Guiye, CHEN Yanwei, LIU Na. Preparation of GSH-Modified Au Nanorods and Their Interaction with Copper Ions^† [J]. Chem. J. Chinese Universities, 2016, 37(7): 1239.
[15]	QI Fenglian, XUE Min, XUE Fei, MENG Zihui, QIU Lili, XU Zhibin, LU Wei. Preparation and Chemical Sense Character of Two-dimensional Colloidal Crystal Heterostructures^† [J]. Chem. J. Chinese Universities, 2015, 36(8): 1612.