One-pot Synthesis and Characterization of Diblock Copolymer via Combining Enzymatic and ATRP

doi:10.7503/cjcu20130078

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (7): 1770.doi: 10.7503/cjcu20130078

• Polymer Chemistry • Previous Articles Next Articles

One-pot Synthesis and Characterization of Diblock Copolymer via Combining Enzymatic and ATRP

SA Zong-Peng¹, LIU Yan-Jing², LI Ya-Peng¹, ZHU Ming¹, LI Yu-Xiang¹, WANG Jing-Yuan¹

1. Alan G MacDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, China;
2. Changchun University of Chinese Medicine, Chiangchun 130023, China

Received:2013-01-22 Online:2013-07-10 Published:2013-06-21
Contact: Li Ya-Peng E-mail:liyapeng@jlu.edu.cn

Abstract

Abstract:

Diblock copolymer poly(n-butyl methacrylate)-block-poly(10-hydroxydecanoate)(PnBA-b-PHD) was prepared by one pot strategy via combination of enzymatic polymerization of 10-hydroxydecanoate(HD) and atom transfer radical polymerization(ATRP) of n-butyl methacrylate(nBA). The obtained copolymer was characterized by ¹H NMR, FTIR and gel permeation chromatography(GPC). The solution properties of diblock copolymer into water in dry state were examined by atom force microscopy(AFM), in which well-dispersed spherical micellar structure in mono-modal pattern was clearly observed with a size value around 135 nm. Whereas the hydrodynamic diameter of the aggregates surrounded in tetrahydrofuran(THF) was determined by dynamic light scattering(DLS) instrument.

Key words: One-pot, Enzymatic self condensation polymerization(eSCP), Atom transfer radieal polymerization(ATRP), Diblock copolymer

CLC Number:

O631

TrendMD:

SA Zong-Peng, LIU Yan-Jing, LI Ya-Peng, ZHU Ming, LI Yu-Xiang, WANG Jing-Yuan. One-pot Synthesis and Characterization of Diblock Copolymer via Combining Enzymatic and ATRP[J]. Chem. J. Chinese Universities, 2013, 34(7): 1770.

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One-pot Synthesis and Characterization of Diblock Copolymer via Combining Enzymatic and ATRP

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