Synthesis, Structure Characterization and Thermochemistry of Pyridine-2,6-dicarboxylic Acid Potassium Hydrogen

doi:10.3969/j.issn.0251-0790.2012.09.035

Abstract

Abstract:

Pyridine-2,6-dicarboxylic acid potassium hydrogen(KHDPC) was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Low-temperature heat capacities of the compound were measured with an automated adiabatic calorimeter over the temperature range from 78 K to 360 K. Experimental heat capacities were fitted by least-squares method and a polynomial equation of heat capacities vs. reduced temperature was obtained. The smoothed molar heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated based on the fitted polynomial equation. A reasonable thermochemical cycle was designed on the basis of a designed reaction of the substance, and standard molar enthalpies of dissolution for the reactants and products of the supposed reaction in the selected solvents were measured by an isoperibol solution-reaction calorimeter, respectively. Eventually, standard molar enthalpy of formation of the compound was derived to be -(1052.69±1.52) kJ/mol by Hess thermochemical cycle.

Key words: Pyridine-2,6-dicarboxylic acid potassium hydrogen(KHDPC), Crystal structure, Low-temperature heat capacity, Standard molar enthalpy of formation

CLC Number:

O642.3

TrendMD:

ZHONG Wen-Wen, DI Ming-Zhe, DI You-Ying. Synthesis, Structure Characterization and Thermochemistry of Pyridine-2,6-dicarboxylic Acid Potassium Hydrogen[J]. Chem. J. Chinese Universities, 2012, 33(09): 2074.

References

[1] Murtha D. P., Walton R. A.. Inorg. Chim. Acta[J], 1974, 8(3): 279-284

[2] ZHONG Xin-Xian(钟新仙), WANG Xiang-Li(王湘利), JIANG Yi-Min(蒋毅民). J. Guangxi Normal University(广西师范大学学报)[J], 2004, 22(1): 60-63

[3] Chen J. T., Di Y. Y., Tan Z. C., Sun L. X.. Chem. Res. Chinese Universities[J], 2007, 23(5): 574-578

[4] Archer D. G.. J. Phys. Chem. Ref. Data[J], 1993, 22: 1441-1453

[5] Di Y. Y., Tan Z. C., Gao S. L., Wang S. X.. J. Chem. Eng. Data[J], 2004, 49: 965-969

[6] HE Dong-Hua(何东华), DI You-Ying(邸友莹), YANG Wei-Wei(杨伟伟), KONG Yu-Xia(孔玉霞), DAN Wen-Yan(淡文彦), TAN Zhi-Cheng(谭志诚). Chem. J. Chinese Universities(高等学校化学学报)[J], 2009, 30(11): 2258-2262

[7] LIU Yu-Pu(刘玉普), DI You-Ying(邸友莹), HE Dong-Hua(何东华), KONG Yu-Xia(孔玉霞), YANG Wei-Wei(杨伟伟), DAN Wen-Yan(淡文彦). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(6): 1227-1230

[8] Yang W. W., Di Y. Y., Li J., Kong Y. X..Chem. Res. Chinese Universities[J], 2010, 26(2): 304-308

[9] Seifert H. J., Funke S..Thermochimica Acta[J], 1998, 320: 1-7

[10] Rychly R., Pekarek V.. J. Chem.Thermodyn.[J], 1977, 9: 391-396

[11] TONG Jing(佟静), SUN Ying-Chun(孙迎春), FANG Da-Wei(房大维), YANG Jia-Zhen(杨家振). Chem. J. Chinese Universities(高等学校化学学报)[J], 2009, 30(6): 1210-1213

[12] YANG Wei-Wei(杨伟伟), KONG Yu-Xia(孔玉霞), DI You-Ying(邸友莹), SHI Quan(史全), TAN Zhi-Cheng(谭志诚). Chem. J. Chinese Universities(高等学校化学学报)[J], 2008, 29(4): 799-804

[13] LI Qiang-Guo(李强国), QU Song-Sheng(屈松生), ZHOU Chuan-Pei(周传佩), LIU Yi(刘义). Chem. J. Chinese Universities(高等学校化学学报)[J], 2000, 21(5): 791-793

[14] YAO Yun-Bin(姚允斌), XIE Tao(解涛), GAO Ying-Min(高英敏). Handbook of Physics and Chemistry(物理化学手册)[M], Shanghai: Press of Science and Technology, 1985: 894

[15] Steele W. V., Chirico R. D., Cowell A. B., Knipmeyer S. E., Nguyen A.. J. Chem. Eng. Data[J], 1997, 42: 1052-1066

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