Surface Modification and Anticorrosive Properties of Polyaniline

doi:10.3969/j.issn.0251-0790.2012.03.037

Abstract

Abstract:

The surface of PANI was modified by octamethylcyclotetrasiloxane(D₄). The effects of reaction temperature, time, the amount of monomer and pH on the grafting effect, dispersibility and corrosion potential were investigated by characterizing cyclic voltammetry(CV), polarization curves(Tafel) and grafting yield of the modified PANI. Besides, the structures and properties of PANI before and after modifying were compared with CV, UV-Vis, FTIR spectra, X-ray diffraction(XRD) and thermogravimetry(TGA). The results indicate that the surface of PANI is modified effectively by D₄, and the dispersibility, dispersibility stability and anti-corrosion of PANI are enhanced significantly.

Key words: Polyaniline, Surface modification, Octamethylcyclotetrasiloxane, Anticorrosion

CLC Number:

O631

TrendMD:

GAN Meng-Yu, LI Zhi-Chun, MA Li, HAO Shao-Na, JIA Chun-Yue, LIU Xing-Min. Surface Modification and Anticorrosive Properties of Polyaniline[J]. Chem. J. Chinese Universities, doi: 10.3969/j.issn.0251-0790.2012.03.037.

[1]	ZHAO Sheng, HUO Zhipeng, ZHONG Guoqiang, ZHANG Hong, HU Liqun. Preparation of Modified Gadolinium/Boron/Polyethylene Nanocomposite and Its Radiation Shielding Performance for Neutron and Gamma-ray [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220039.
[2]	YANG Sixian, ZHONG Wenyu, LI Chaoxian, SU Qiuyao, XU Bingjia, HE Guping, SUN Fengqiang. Photochemical Fabrication and Performance of Polyaniline Nanowire/SnO₂ Composite Photocatalyst [J]. Chem. J. Chinese Universities, 2021, 42(6): 1942.
[3]	SHI Ying, HU Guangjian, WU Minjie, LI Feng. Applications of Low Temperature Plasma for the Materials in Li-ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(5): 1315.
[4]	JI Shaobo, CHEN Xiaodong. Surface and Interface Chemistry in Flexible Electronics [J]. Chem. J. Chinese Universities, 2021, 42(4): 1074.
[5]	YAN Fanyong, SUN Zhonghui, PANG Jiping, JIANG Yingxia, CHEN Yuan. Functionalized Carbon Dots of Benzothiazine Derivatives for Detection of Quercetin in Ginkgo Biloba Tea [J]. Chem. J. Chinese Universities, 2020, 41(8): 1768.
[6]	PENG Xinyan, LIU Yunhong, LI Jiawen, FENG Yilong, WANG Hanchun. Preparation and Characterization of Tannin/Zwitterionic Modified Oil-water Separation Membrane ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1337.
[7]	CHEN Liangdan,ZOU Wei,WU Liang,XIA Fanjie,HU Zhiyi,LI Yu,SU Baolian. Nano-Al₂O₃ Coated Li-rich Cathode Material Li_{1. 2}Ni_0.13Co_0.13Mn_0.54O₂ for Highly Improved Lithium-ion Batteries ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1329.
[8]	REN Wen, ZHANG Guoli, YAN Han, HU Xinghua, LI Kun, WANG Jingfeng, LI Ruiqi. Preparation of Superhydrophobic Polyaniline/Polytetrafluoroethylenethylene Composite Membrane and Its Separation Ability for Oil-Water Emulsion ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 846.
[9]	LIU Shuaizhuo,ZHANG Qian,LIU Ning,XIAO Wenyan,FAN Leiyi,ZHOU Ying. One-step Synergistic Hydrophobic Modification of Melamine Sponge and Its Application ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 521.
[10]	ZHANG Xinyu, WANG Hong, FANG Yun, FAN Ye. Stimuli-responsive Fe₃O₄ Nanoparticle Modified by Conjugated Linoleic Acid [J]. Chem. J. Chinese Universities, 2020, 41(11): 2519.
[11]	LING Xuxia, LONG Zhu, WANG Shihua, LI Zhiqiang, GUO Shuai, ZHANG Dan. Surface Modified Aramid Pulp with Polyaniline and Conductivity of Its Paper-based Materials [J]. Chem. J. Chinese Universities, 2020, 41(11): 2553.
[12]	WANG Yihan,YIN Qiang,DU Kai,YIN Qinjian. Polypyrrole/Polyaniline Nanocomposite Nanotubes with Enhanced Thermoelectric Properties ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 175.
[13]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[14]	MAO Long, LIU Yuejun, FAN Shuhong. Preparation and Properties of Polypyrrole Modified Layered Clay/poly(ε-caprolactone) Antibacterial Nanocomposites [J]. Chem. J. Chinese Universities, 2019, 40(8): 1726.
[15]	SUI Jiayang, LIU Xiaoyang, QIAN Miaomiao, ZHU Yanchao, XUE Beichen, FENG Yi, TIAN Yumei, WANG Xiaofeng. Surface Modification of Silica/carbon Black Derived from Rice Husks and Its Influence on Natural Rubber Composites^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1561.

Surface Modification and Anticorrosive Properties of Polyaniline

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments