高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (11): 1597.

• 论文 • 上一篇    下一篇

[Cu(NBOCTB)](ClO4)2·2DMF的合成、晶体结构和热分解过程研究

李晓燕   

  1. 山东大学化学系, 济南, 250100
  • 收稿日期:1993-12-25 修回日期:1994-04-29 出版日期:1994-11-24 发布日期:1994-11-24
  • 作者简介:李晓燕,女,30岁,硕士,讲师.
  • 基金资助:

    国家自然科学基金

Synthesis, Crystal Structure and Thermal Decomposition of[Cu(NBOCTB)](ClO4)2·2DMF

Ll Xiao-Yan   

  1. Department of Chemistry, Shandong university, Jinan, 250100
  • Received:1993-12-25 Revised:1994-04-29 Online:1994-11-24 Published:1994-11-24

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摘要： 制备了二(N,N-二甲基甲酰胺)-高氯酸N,N,N',N'-四[(1'-苄基-2'-苯并咪唑)甲基]-1,2-环己二胺合铜(Ⅱ){[Cu(NBOCTB)](ClO4)2·2DMF}.X射线测定表明其晶体属三斜晶系,空间群P1,晶胞参数α=1.1851(5)nm,b=1.2255(3)nm,c=2.5237(5)nm;α=92.37(2)°,β=98.01(2)°,γ=107.82(3)°,V=3.442(4)nm3,M=1403.93,Z=2,Dx=1.36g/cm3,μ=4.60cm(-1),F(000)=1470.TG-DTG技术研究结果表明,配合物的热分解过程分为以下4个阶段:(19941106-1597-1.jpg)

关键词: 铜配合物, 晶体结构, 热分解

Abstract: The complex of Cu(Ⅱ)with N, N, N'N'-tetra[1'-benzyl-2'-benzimidazol)methyl]-trans-1, 2-diaminocyclohexane(NBOCTB), [Cu(NBOCTB)](ClO4)2·2DMF, wasprepared. The crystal of the complex belongs to triclinic system and P1 space group with a=1.1851(5)nm, b=1.2255(3)nm, c=2.5237(5)nm;a=92.37(2)°, β=98.01(2)°, γ=107.82(3)°;V=3.442(4)nm3, M=1043.93, Z=2, Dx=1.36g/cm3, μ=4.60 cm-1, F(000)=1470. The thermal decompostion of the complex was studied by TG-DTGtechniques.The process of the decomposition can be divided into four stages:(19941106-1597-1.jpg)

Key words: Copper complex, Crystal structure, Thermal decomposition

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