高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (4): 706.

• 研究简报 • 上一篇    下一篇

6-叠氮-6-脱氧凝聚多糖的选择性一步合成

博·格日勒图, 胡日查, 刘国光, 钟桂云   

  1. 内蒙古大学高分子科学研究所, 呼和浩特 010021
  • 收稿日期:2000-03-21 出版日期:2001-04-24 发布日期:2001-04-24
  • 通讯作者: 博·格日勒图(1957年出生),男,博士,教授,主要从事生理活性多糖及蒙药成分研究.
  • 基金资助:

    国家自然科学基金(批准号:20064001);科技部重点攻关项目(批准号:96-901-06-69)资助

A Direct Regioselective Synthesis of 6-Azido-6-deoxy-curdlan

BORJHAN Gereltu, HU Ri-Cha, LIU Guo-Guang, ZHONG Gui-Yun   

  1. Institute of Polymer Science, College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhehot 010021, China
  • Received:2000-03-21 Online:2001-04-24 Published:2001-04-24

关键词: 叠氮化多糖, 凝聚多糖, 脱氧凝聚多糖

Abstract: 6-Azido-6-deoxy-curdlan(ADC) was synthesized by a direct regioselective reaction of curdlan with triphenylphosphine, carbon tetrabromide and sodium azide(NaN3) in DMFat room temperature. The structure of ADCwas determined by 13C NMR, IRand elemental analysis.

Key words: Azido-group containing polysaccharide, Curdlan, Deoxy-curdlan

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