高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (2): 303.

• 研究简报 • 上一篇    下一篇

C60与n-Bu3SnH的自由基反应研究

余益民1, 郭兴华1, 刘子阳1, 刘淑莹1, 傅芳信2, 钱明星2   

  1. 1. 中国科学院长春应用化学研究所, 长春 130022;
    2. 东北师范大学化学系
  • 收稿日期:1995-06-23 出版日期:1996-02-24 发布日期:1996-02-24
  • 通讯作者: 刘淑莹
  • 作者简介:佘益民,男,30岁,博士研究生.
  • 基金资助:

    国家自然科学基金

A Study of the Radical Reaction of C60 with n-Bu3SnH

SHE Yi-Min1, GUO xing-Hua1, LIU Zi-Yang1, LIU Shu-Ying1, FU Fang-Xin2, QIAN Ming-Xing2   

  1. 1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun;
    2. Department of Chemistry, Northeast Normal University
  • Received:1995-06-23 Online:1996-02-24 Published:1996-02-24

PDF (PC)

关键词: 自由基反应, 富勒烯, 三丁基锡氢化物, 自由基海绵

Abstract: The reaction of buckministerfullerene(C60)with tri-n-butyltin hydride(n-Bu3SnH)in toluene solution has been investigated.According to mass spectrometry analysis,the products of above reaction are C60(BuH)n(n=1～3) and BuxSnyHz(x=3～8,y=1～4,z=0～3).The reaction maybe provide a new method for the synthesis of alkylated fullerene derivatives.Where C60 also takes a role of a catalysis of organtic-tin polymerization,The radical reaction mechanism has been discussed.

Key words: Radical reaction, Fullerene, Tri-n-butyltin hydride, Radical sponge

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