高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (7): 1335.

• 研究快报 • 上一篇    下一篇

一种新的聚磷腈反应中间体的制备及含C60基团聚磷腈的合成

李振, 秦金贵   

  1. 武汉大学化学与分子科学学院, 武汉 430072
  • 收稿日期:2003-02-12 出版日期:2003-07-24 发布日期:2003-07-24
  • 通讯作者: 秦金贵(1947年出生),男,博士,教授,博士生导师,主要从事光电功能材料化学的研究.E-mail:jgqin@whu.edu.cn E-mail:jgqin@whu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:90201002)资助

Syntheses of a Novel Intermediate Polyphosphazene and C60-contained Polyphosphazenes

LI Zhen, QIN Jin-Gui   

  1. College of Chemistry and Molycular Science, Wuhan University, Wuhan 430072, China
  • Received:2003-02-12 Online:2003-07-24 Published:2003-07-24

关键词: 聚磷腈, 中间体, C60

Abstract: In this paper, a novel synthetic strategy was developed to prepare functional polyphosphazenes. This strategy was successfully applied to synthesize the first C60-contained polyphosphazenes. Thus, polyphosphazene that contains azido groups as the side groups was obtained by a direct reaction. And then the azido groups reacted with C60 moieties to yield the C60-contained polyphosphazenes. The polymers were well characterized and exhibit an excellent solubility in common organic solvents.

Key words: Polyphosphazene, Intermediate, C60

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