高等学校化学学报

高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (1): 28.

• 研究快报 • 上一篇    下一篇

三维无机-有机杂化骨架微孔材料──[Co3(BTC)(HBTC)(H2BTC)(C2H4O2)3]·3(DMF)·6(H3O)的合成与结构

方千荣, 石鑫, 辛明红, 吴刚, 田歌, 朱广山, 李亚丰, 叶玲, 王春雷, 张震东, 唐璐璐, 裘式纶   

  1. 吉林大学化学学院, 无机合成与制备化学国家重点实验室, 长春 130023
  • 收稿日期:2002-09-29 出版日期:2003-01-24 发布日期:2003-01-24
  • 通讯作者: 裘式纶(1948年出生),男,博士,教授,博士生导师,从事无机固体材料化学研究.E-mail:sqiu@mail.jlu.edu.cn E-mail:sqiu@mail.jlu.edu.cn
  • 基金资助:

    国家重大基础研究计划“973”项目(批准号:G2000077507);国家自然科学基金(批准号:29873017;20101004)资助

A 3-D Inorganic-organic Hybrid Framework Microporous Material──Synthesis and Characteristic of [Co3(BTC)(HBTC)(H2BTC)(C2H4O2)3]·3(DMF)·6(H3O)

FANG Qian-Rong, SHI Xin, XIN Ming-Hong, WU Gang, TIAN Ge, ZHU Guang-Shan, LI Ya-Feng, YE Ling, WANG Chun-Lei, ZHANG Zhen-Dong, TANG Lu-Lu, QIU Shi-Lun   

  1. College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2002-09-29 Online:2003-01-24 Published:2003-01-24

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关键词: 晶体结构, 无机-有机杂化骨架结构, 微孔材料

Abstract: Compound [Co3(BTC)(HBTC)(H2BTC)(C2H4O2) 3]·3(DMF)·6(H3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1.821 6(4) nm, β=128.16(3) °, V=6.329(2) nm3, Z=2 , Dc=20.200 Mg/m3, M r= 1 314.744, μ=10.274 mm-1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.

Key words: Crystal structure, Inorganic-organic hybrid framework, Microporous material

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