高等学校化学学报

高等学校化学学报

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氮杂酞菁铜aza-CuPc的合成与晶体结构

姜文海1, 王旭2, 马春雨3, 于书坤1, 叶开其2, 常玉春1,3, 杜国同1,3   

    1. 吉林大学集成光电子国家重点实验室, 长春 130012;
    2. 吉林大学超分子结构与材料教育部重点实验室, 长春 130012;
    3. 大连理工大学三束材料改性国家重点实验室, 大连 116023
  • 收稿日期:2006-02-22 修回日期:1900-01-01 出版日期:2006-12-10 发布日期:2006-12-10
  • 通讯作者: 杜国同

Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine

JIANG Wen-Hai1, WANG Xu2, MA Chun-Yu3, YU Shu-Kun1, YE Kai-Qi2, CHANG Yu-Chun1,3, DU Guo-Tong1,3
   

    1. State Key Laboratory on Integrated Optoelectronics, Jilin University, Changchun 130012, China;
    2. Key Laboratory for Superamolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130012, China;
    3. State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Dalian 116023, China
  • Received:2006-02-22 Revised:1900-01-01 Online:2006-12-10 Published:2006-12-10
  • Contact: DU Guo-Tong

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被引次数

6

摘要： 本文报道在固相条件下合成氮杂酞菁铜原料, 借助同步辐射光源进行单晶结构测试, 通过物理方法获得了其单晶结构数据.

关键词: 固相法合成, 氮杂酞菁铜, 同步辐射, 晶体结构

Abstract: The azaanalog of copper phthalocyanine(aza-CuPc) complex C24H8CuN16 was prepared by the so-lid phase synthesis technology and its single crystals was characterized by high power X-ray from the synchrotron radiation. The crystal belongs to monoclinic system, space group P21/n with a=1.612 3(3) nm, b=0.529 40(11) nm, c=1.906 4(4) nm, β=105.25(3)°, V=1.569 9(5) nm, Z=2, Mr=584.00, Dc=1.235 g/cm3, F(000)=586, the final R=0.063 1 and wR=0.153 9 for 757 observed reflections with I>2σ(I), GOF=1.340.

Key words: Solid phase synthesis, Azaanalog of copper phthalocyanine, Synchrotron radiation, Crystal structure

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