基于纳米晶晶格热胀冷缩的高灵敏度荧光纳米温度计

doi:10.7503/cjcu20131065

摘要/Abstract

摘要：

有效测量纳微米尺度范围温度及物体表面温度梯度分布需要研发各种类型的纳米尺度温度计来实现. 半导体纳米晶由于具有尺寸效应引起光致发光(荧光)效应, 其具有的热胀冷缩的性质会使得温度变化引起纳米晶晶格收缩或膨胀, 从而引起荧光光谱的变化, 进而为设计制备高灵敏度温度计奠定基础. 结合前期相关工作, 本文总结了基于纳米晶的各种荧光纳米温度计, 阐述不同类型纳米温度计的特性, 为这一前沿领域研究提供启发.

关键词: 荧光纳米晶, 纳米温度计, 晶格膨胀, 表面修饰

Abstract:

Temperature is a critical thermodynamic parameter in many biological and biotechnological processes. And its measurement is often required for both scientific research and industrial applications. However, measuring the local temperature and temperature gradient in the nanoscale regime remains an enormous challenge. Due to quantum confinement effect, semiconductor nanocrystals(NCs) show unique size-dependent optical property, which has got people’s extensive concern in the past few years and supplies a new approach towards measuring temperature in the nanoscale regime. In this review article, various NCs-based thermometers were systematically summarized with the aim to inspire the researchers engaged in this field.

Key words: Fluorescent nanocrystal, Nanothermometer, Lattice dilation, Surface modification

中图分类号:

O631

TrendMD:

周鼎, 徐晓薇, 刘敏, 张皓, 孙宏晨. 基于纳米晶晶格热胀冷缩的高灵敏度荧光纳米温度计. 高等学校化学学报, 2014, 35(2): 205.

ZHOU Ding, XU Xiaowei, LIU Min, ZHANG Hao, SUN Hongchen. High Sensitivity Luminescence Nanothermometry on the Basis of Lattice Dilation of Nanocrystals^†. Chem. J. Chinese Universities, 2014, 35(2): 205.

图/表 7

Fig.1 Fluorescence spectra of CdTe nanocrystals(NCs) at different temperatures(A), fluorescence peak intensity of CdTe NCs as a function of temperature(B) and fluorescence peak intensity of CdTe NCs as a function of temperature with an irreversible effect after heating to 140 ℃(C)[3]

Fig.2 Schematic diagram of noncontact temperature characterization using NCs through emission spectral shifts(A) and representative spectrum-position image containing several single NCs(B)[52]

Fig.3 Peak emission wavelength of the CdSe-NCs fluorescence as a function of the gold nanorod solution temperature(A), schematic diagram of the double beam confocal microscope(B) and fluorescence emission spectrum obtained for the CdSe-NCs incorporated into the gold nanorod solution under 488 nm excitation in the presence/absence of optical excitation of the surface plasmon resonance(SPR) of gold nanorods(C)[50]

Fig.4 Gradient fluorescence of α-CD- and β-CD-decorated CdTe NCs aqueous solution in quartz tubes(A), fluorescence spectra of β-CD-decorated CdTe NCs that are measured with the increase of temperature from -35 ℃ to 90 ℃ at a step of 5 ℃(red solid) and that from 90 ℃ to -35 ℃(white dash)(B), temperature-dependent fluorescence peak position of β-CD-decorated CdTe NCs(C), and CIE chromaticity diagram showing the temperature dependence of the (x, y) color coordinates of β-CD-decorated CdTe NCs(D)[81]

Fig.5 β-CD-decorated CdTe NCs as the nanothermometer to exhibit the photothermal behavior of PPy-enveloped branched Au NPs[81] (A),(B) Optical photographs of CdTe and Au-CdTe mixture without(A) and with 808 nm irradiation(B); (C),(D) the dependence of the fluorescence spectra(C) and the shifts of peak positions(D) on the irradiation duration. Insets of (D): the fluorescent images of Au-CdTe mixture before and after 11 min irradiation. (E) Optical photograph of Au-CdTe film. Temperature maps of Au-CdTe film with 0 s(F), 30 s(G) and 60 s(H) irradiation, after which the film is cooled down to room temperature(I). The laser power density is 3 W/cm2.

Fig.6 Variable-temperature PL spectra of colloidal Zn1-xMnxSe/ZnS/CdS/ZnS NCs, measured in octadecene under nitrogen[59] (A) Spectra were normalized to total integrated intensity; (B) thermometric response curve plotting Iexc/Itot vs. temperature for these NCs, a maximum slope of 7.3×10-3 ℃-1 was obtained.

Fig.7 Si NCs act as excellent nanothermometers through the FLIM technique[99](A) Fluorescence decay curves corresponding to Si NCs at different temperatures; (B) temperature variation of FLT obtained for Si NCs; (C) schematic diagram of the experimental setup used to monitor local heating experiment; (D) pseudocolor thermal distribution images of the temperature-sensitive Si NCs aqueous solution; (E) pseudocolor thermal imaging of a character pattern.

参考文献 105

[1]	Clausen T., van Hardeveld C., Everts M. E., Physiol. Rev., 1991, 71(3), 733—774
[2]	Narberhaus F., Waldminghaus T., Chowdhury S., FEMS Microbiol. Rev., 2006, 30(1), 3—16
[3]	Wang S. P., Westcott S., Chen W., J. Phys. Chem. B, 2002, 106(43), 11203—11209
[4]	Lee J., Kotov N. A., Nano Today, 2007, 2(1), 48—51
[5]	Alivisatos A. P., Science, 1996, 271(5251), 933—937
[6]	Klimov V. I., Mikhailovsky A. A., Xu S., Malko A., Hollingsworth J. A., Leatherdale C. A., Eisler H. J., Bawendi M. G., Science, 2000, 290(5490), 314—317
[7]	Murray C. B., Norris D. J., Bawendi M. G., J. Am. Chem. Soc., 1993, 115(19), 8706—8715
[8]	Rajh T., Nozik A. J., J. Phys. Chem., 1993, 97(46), 11999—12003
[9]	Nirmal M., Brus L., Acc. Chem. Res., 1999, 32(5), 407—414
[10]	Chan W. C. W., Nie S. M., Science, 1998, 281(5385), 2016—2018
[11]	Cao Y. W., Banin U., J. Am. Chem. Soc., 2000, 122(40), 9692—9702
[12]	Tang K. B., Qian Y. T., Zeng J. H., Yang X. G., Adv. Mater., 2003, 15(5), 448—450
[13]	Gaponik N., Talapin D. V., Rogach A. L., Hoppe K., Shevchenko E. V., Kornowski A., Eychmüller A., Weller H., J. Phys. Chem. B, 2002, 106(29), 7177—7185
[14]	Rogach A. L., Franzl T., Klar T. A., Feldmann J., Gaponik N., Lesnyak V., Shavel A., Eychmüller A., Rakovich Y. P., Donegan J. F., J. Phys. Chem. C, 2007, 111(40), 14628—14637
[15]	Gaponik N., Rogach A. L., Phys. Chem. Chem. Phys., 2010, 12(31), 8685—8693
[16]	Bao H. B., Gong Y. J., Li Z., Gao M. Y., Chem. Mater., 2004, 16(20), 3853—3859
[17]	Zhang H., Lu G., Ji X. L., Li Z., Yang B., Chem. J. Chinese Universities, 2003, 24(1), 178—180
	(张皓, 陆广, 纪秀磊, 李哲, 杨柏.高等学校化学学报,2003, 24(1), 178—180)
[18]	Tang Z. Y., Zhang Z. L., Wang Y., Glotzer S. C., Kotov N. A., Science, 2006, 314(5797), 274—278
[19]	Traore Z. S., Su X. G., Chem. Res. Chinese Universites, 2012, 28(4), 604—608
[20]	Zhang H., Yang B., Chem. J. Chinese Universities, 2008, 29(2), 217—229
	(张皓, 杨柏.高等学校化学学报,2008, 29(2), 217—229)
[21]	He Y., Sai L. M., Lu H. T., Hu M., Lai W. Y., Fan Q. L., Wang L. H., Huang W., Chem. Mater., 2007, 19(3), 359—365
[22]	Zheng Y. G., Gao S. J., Ying J. Y., Adv. Mater., 2007, 19(3), 376—380
[23]	Li Y. B., Zhang H. X., Guo C. X., Hu G. Q., Du H. Y., Jin M. H., Huang P. L., Sun Z. Z., Yang W. S., Chem. Res. Chinese Universites, 2012, 28(2), 276—281
[24]	Zou L., Gu Z. Y., Zhang N., Zhang Y. L., Fang Z., Zhu W. H., Zhong X. H., J. Mater. Chem., 2008, 18(24), 2807—2815
[25]	Manna L., Scher E. C., Alivisatos A. P., J. Am. Chem. Soc., 2000, 122(51), 12700—12706
[26]	Peng X. G., Manna L., Yang W. D., Wickham J., Scher E., Kadavanich A., Alivisatos A. P., Nature, 2000, 404(6773), 59—61
[27]	Peng Z. A., Peng X. G., J. Am. Chem. Soc., 2001, 123(7), 1389—1395
[28]	Wang Y. P., Zhang K., Wei H. T., Meng Q. N., Zhou D., Jiang L. M. Yang B., Chem. J. Chinese Universities, 2010, 31(11), 2153—2156
	(王燕萍, 张恺, 魏浩桐, 孟庆男, 周鼎, 姜力铭, 杨柏.高等学校化学学报,2010, 31(11), 2153—2156)
[29]	Kumar S., Nann T., Small, 2006, 2(3), 316—329
[30]	Shen H. B., Wang H. Z., Chen X., Niu J. Z., Xu W., Li X. M., Jiang X. D., Du Z., Li L. S., Chem. Mater., 2010, 22(16), 4756—4761
[31]	Wang M. P., Lin J. H., Shan C. S., Chem. Res. Chinese Universites, 2011, 27(4), 540—542
[32]	Wang C. X., Wang Y., Xu L., Shi X. D., Li X. W., Xu X. W., Sun H., Yang B., Lin Q., Small, 2013, 9(3), 413—420
[33]	Swafford L. A., Weigand L. A., Bowers M. J., McBride J. R., Rapaport J. L., Watt T. L., Dixit S. K., Feldman L. C., Rosenthal S. J., J. Am. Chem. Soc., 2006, 128(37), 12299—12306
[34]	Regulacio M. D., Han M. Y., Acc. Chem. Res., 2010, 43(5), 621—630
[35]	Wang C., Zhang D., Xu L., Jiang Y., Dong F., Yang B., Yu K., Lin Q., Angew. Chem. Int. Ed., 2011, 50(33), 7587—7591
[36]	Brites C. D. S., Lima P. P., Silva N. J. O., Millán A., Amaral V. S., Palacio F., Carlos L. D., Nanoscale, 2012, 4(16), 4799—4829
[37]	Jaque D., Vetrone F., Nanoscale, 2012, 4(15), 4301—4326
[38]	McLaurin E. J., Bradshaw L. R., Gamelin D. R., Chem. Mater., 2013, 25(8), 1283—1292
[39]	Yu W. W., Peng X. G., Angew. Chem. Int. Ed., 2002, 41(13), 2368—2371
[40]	Warner J. H., Tilley R. D., Adv. Mater., 2005, 17(24), 2997—3001
[41]	Bao H. F., Wang E. K., Dong S. J., Small, 2006, 2(4), 476—480
[42]	Walker G. W., Sundar V. C., Rudzinski C. M., Wun A. W., Bawendi M. G., Nocera D. G., Appl. Phys. Lett., 2003, 83(17), 3555—3557
[43]	Lee J., Govorov A. O., Kotov N. A., Angew. Chem. Int. Ed., 2005, 117(45), 7605—7608
[44]	Joshi A., Narsingi K. Y., Manasreh M. O., Davis E. A., Weaver B. D., Appl. Phys. Lett., 2006, 89(13), 131907
[45]	Al Salman A., Tortschanoff A., Mohamed M. B., Tonti D., van Mourik F., Chergui M., Appl. Phys. Lett., 2007, 90(9), 093104
[46]	Valerini D., Cretí A., Lomascolo M., Manna L., Cingolani R., Anni M., Phys. Rev. B, 2005, 71(23), 235409
[47]	Nonoguchi Y., Nakashima T., Kawai T., J. Phys. Chem. C, 2007, 111(32), 11811—11815
[48]	Pugh-Thomas D., Walsh B. M., Gupta M. C., Nanotechnology, 2011, 22(18), 185503
[49]	Chattopadhyay S., Sen P., Thomas Andrews J., Kumar Sen P., J. Appl. Phys., 2012, 111(3), 034310
[50]	Maestro L. M., Haro-González P., Coello J. G., Jaque D., Appl. Phys. Lett., 2012, 100(20), 201110
[51]	Yue Y., Wang X. W., Nano Rev., 2012, 3(0), 11586
[52]	Li S., Zhang K., Yang J. M., Lin L. W., Yang H., Nano Lett., 2007, 7(10), 3102—3105
[53]	Vetrone F., Naccache R., Zamarrón A., Juarranz dela Fuente A., Sanz-Rodríguez F., Martinez Maestro L., Martín Rodriguez E., Jaque D., García Solé J., Capobianco J. A., ACS Nano, 2010, 4(6), 3254—3258
[54]	Vlaskin V. A., Janssen N., van Rijssel J., Beaulac R., Gamelin D. R., Nano Lett., 2010, 10(9), 3670—3674
[55]	Fischer L. H., Harms G. S., Wolfbeis O. S., Angew. Chem. Int. Ed., 2011, 50(20), 4546—4551
[56]	Zhang W., He X. W., Li W. Y., Zhang Y. K., Chem. Commun., 2012, 48(12), 1757—1759
[57]	Chen P. C., Chen Y. N., Hsu P. C., Shih C. C., Chang H. T., Chem. Commun., 2013, 49(16), 1639—1641
[58]	Hsia C. H., Wuttig A., Yang H., ACS Nano, 2011, 5(12), 9511—9522
[59]	McLaurin E. J., Vlaskin V. A., Gamelin D. R., J. Am. Chem. Soc., 2011, 133(38), 14978—14980
[60]	Albers A. E., Chan E. M., McBride P. M., Ajo-Franklin C. M., Cohen B. E., Helms B. A., J. Am. Chem. Soc., 2012, 134(23), 9565—9568
[61]	Feng J., Tian K. J., Hu D. H., Wang S. Q., Li S. Y., Zeng Y., Li Y., Yang G. Q., Angew. Chem. Int. Ed., 2011, 50(35), 8072—8076
[62]	Liang R. Z., Tian R., Shi W. Y., Liu Z. H., Yan D. P., Wei M., Evans D. G., Duan X., Chem. Commun., 2013, 49(10), 969—971
[63]	Zhou D., Lin M., Liu X., Li J., Chen Z. L., Yao D., Sun H. Z., Zhang H., Yang B., ACS Nano, 2013, 7(3), 2273—2283
[64]	Wise F. W., Acc. Chem. Res., 2000, 33(11), 773—780
[65]	Narayanaswamy A., Feiner L. F., van Der Zaag P. J., J. Phys. Chem. C, 2008, 112(17), 6775—6780
[66]	Dai Q. Q., Zhang Y., Wang Y. N., Hu M. Z., Zou B., Wang Y. D., Yu W. W., Langmuir, 2010, 26(13), 11435—11440
[67]	Yeon Woo J., Kumar Tripathy S., Kim K., Han C. S., Appl. Phys. Lett., 2012, 100(6), 063105
[68]	Nair P. V., Thomas K. G., J. Phys. Chem. A Lett., 2010, 1(14), 2094—2098
[69]	Califano M., Franceschetti A., Zunger A., Nano Lett., 2005, 5(12), 2360—2364
[70]	Kippeny T. C., Bowers M. J., Dukes A. D., McBride J. R., Orndorff R. L., Garrett M. D., Rosenthal S. J., J. Chem. Phys., 2008, 128(8), 084713
[71]	Califano M., Gómez-Campos F. M., Nano Lett., 2013, 13(5), 2047—2052
[72]	Wu W. Z., Yu D. Q., Ye H. A., Gao Y. C., Chang Q., Nanoscale Res. Lett., 2012, 7(1), 301
[73]	Varshni Y. P., Physica, 1967, 34(1), 149—154
[74]	Chin P. T. K., de Mello Donegá C., van Bavel S. S., Meskers S. C. J., Sommerdijk N. A. J. M., Janssen R. A. J., J. Am. Chem. Soc., 2007, 129(48), 14880—14886
[75]	Narayanaswamy A., Feiner L. F., Meijerink A., van der Zaag P. J., ACS Nano, 2009, 3(9), 2539—2546
[76]	Wen X. M., Sitt A., Yu P., Toh Y. R., Tang J., Phys. Chem. Chem. Phys., 2012, 14(10), 3505—3512
[77]	Bonghwan C., Jiwon B., Juwon P., Cherlhyun J., Jong Hwa C., Jong-Bong L., Taiha J., Sungjee K., J. Phys. Chem. C, 2011, 115(2), 436—442
[78]	Zhou D., Zhang H., Small, 2013, 9(19), 3195—3197
[79]	Zhong X. H., Feng Y. Y., Knoll W., Han M. Y., J. Am. Chem. Soc., 2003, 125(44), 13559—13563
[80]	Liu Y., Yao D., Shen L., Zhang H., Zhang X. D., Yang B., J. Am. Chem. Soc., 2012, 134(17), 7207—7210
[81]	Zhou D., Lin M., Chen Z. L., Sun H. Z., Zhang H., Sun H. C., Yang B., Chem. Mater., 2011, 23(21), 4857—4862
[82]	Betzel C., Saenger W., Hingerty B. E., Brown G. M., J. Am. Chem. Soc., 1984, 106(24), 7545—7557
[83]	Wood D. J., Hruska F. E., Saenger W., J. Am. Chem. Soc., 1977, 99(6), 1735—1740
[84]	Kozár T., Venanzi C. A., J. Mol. Struct., 1997, 395/396, 451—468
[85]	Lipkowitz K. B., Chem. Rev., 1998, 98(5), 1829—1873
[86]	Schneider H. J., Hacket F., Rüdiger V., Ikeda H., Chem. Rev., 1998, 98(5), 1755—1785
[87]	Schöps O., Le Thomas N., Woggon U., Artemyev M. V., J. Phys. Chem. B, 2006, 110(5), 2074—2079
[88]	Sakaue H., Aikawa A., Iijima Y., Sens. Actuators B, 2010, 150(2), 569—573
[89]	Yoo J. H., Park S. J., Kim J. S., Mol. Cryst. Liq. Cryst., 2010, 519(1), 62—68
[90]	Jaschinski E., Wehner M., Appl. Phys. A, 2012, 107(3), 691—696
[91]	Jaque D., Maestro L. M., Escudero E., Rodríguez E. M., Capobianco J. A., Vetrone F., Juarranz dela Fuente A., Sanz-Rodríguez F., Iglesias-de la Cruz M. C., Jacinto C., Rocha U., García Solé J., J. Lumin., 2013, 133(1), 249—253
[92]	Haro-González P., Martínez-Maestro L., Martín I. R., García-Solé J., Jaque D., Small, 2012, 8(17), 2652—2658
[93]	Rojas M. T., Königer R., Stoddart J. F., Kaifer A. E., J. Am. Chem. Soc., 1995, 117(1), 336—343
[94]	Van de Broek B., Devoogdt N., D'Hollander A., Gijs H. L., Jans K., Lagae L., Muyldermans S., Maes G., Borghs G., ACS Nano, 2011, 5(6), 4319—4328
[95]	Adachi S., Handbook on Physical Properties of Semiconductors, Springer,Berlin, 2004, 3
[96]	McDowell G. R., Holmes-Smith A. S., Uttamlal M., Wallace P. A., Faichnie D. M., Graham A., McStay D., J. Phys.: Conf. Ser., 2013, 450(1), 012008
[97]	Han B., Hanson W. L., Bensalah K., Tuncel A., Stern J. M., Cadeddu J. A., Ann. Biomed. Eng., 2009, 37(6), 1230—1239
[98]	Freddi S., Sironi L., D’Antuono R., Morone D., Donà A., Cabrini E., D’Alfonso L., Collini M., Pallavicini P., Baldi G., Maggioni D., Chirico G., Nano Lett., 2013, 13(5), 2004—2010
[99]	Li Q., He Y., Chang J., Wang L., Chen H. Z., Tan Y. W., Wang H. Y., Shao Z. Z., J. Am. Chem. Soc., 2013, 135(40), 14924—14927
[100]	Lee C. G., Uehara M., Yamaguchi Y., Nakamura H., Maeda H., IFMBE Proceedings, 2007, 14(1), 254—257
[101]	Wang J. W., Huang L., Appl. Phys. Lett., 2011, 98(11), 113102
[102]	Haro-González P., Ramsay W. T., Maestro L. M., del Rosal B., Santacruz-Gomez K., del Carmen Iglesias-dela Cruz M., Sanz-Rodríguez F., Chooi J. Y., Sevilla P. R., Bettinelli M., Choudhury D., Kar A. K., Solé J. G., Jaque D., Paterson L., Small, 2013, 9(12), 2162—2170
[103]	Nonoguchi Y., Nakashima T., Kawai T., J. Phys. Chem. C, 2009, 113(27), 11464—11468
[104]	Blumling D. E., Tokumoto T., McGill S., Knappenberger K. L. Jr., Phys. Chem. Chem. Phys., 2012, 14(31), 11053—11059
[105]	Bol A. A., van Beek R., Ferwerda J., Meijerink A., J. Phys. Chem. Solids, 2003, 64(2), 247—252