高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (8): 1018.

• 论文 • 上一篇    下一篇

含表面活性剂多元配合物体系中化学平衡的研究

张贵珠, 高志, 何锡文, 史慧明   

  1. 南开大学化学系, 天津, 300071
  • 收稿日期:1990-02-13 出版日期:1991-08-24 发布日期:1991-08-24
  • 通讯作者: 张贵珠
  • 基金资助:

    国家自然科学基金

Studies on the Chemical Equilibrium in the Multicomponent Complex System Containing Surfactant

Zhang Gui-zhu, Gao Zhi, He Xi-wen, Shi Hui-ming   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1990-02-13 Online:1991-08-24 Published:1991-08-24

摘要: 提出以光谱法与电导法研究含表面活性剂多元配合物体系的化学平衡,从定量方程式可知,三元配合物转化率最高时,相应的表面活性剂最佳浓度与有关组分间缔合数和稳定常数密切相关。

关键词: 多元配合物, 化学平衡, 光谱法, 电导法, 三苯甲烷染料

Abstract: In this work, the spectrometry and conductometry were applied to studying the chemical e-quilibrium of the multicomponent complexes containing surfactant. The optimum concentration of surfactant is relative to both association numbers and stability constants of some components when there is. a maximum productive rate of multicomponent complex in the system. The optimum work condition can be deduced and the surfactant effect can be predicted.

Key words: Multicomponent complex, Chemical equilibrium, Spectrometry, Conductometry, Triph-enylmethane dye

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