高等学校化学学报

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金属有机骨架复合材料RhB/MOF-5的制备及其发光性质

王海君1,2, 朱广山1, 张可勇2, 孙福兴1, 裘式纶1   

    1. 吉林大学化学学院, 无机合成与制备国家重点实验室, 长春 130012;
    2. 齐齐哈尔医学院药学院, 齐齐哈尔 161006
  • 收稿日期:2008-04-23 修回日期:1900-01-01 出版日期:2009-01-10 发布日期:2009-01-10
  • 通讯作者: 朱广山

Preparation and Fluorescence Property of Metal-organic Framework Composite RhB/MOF-5

WANG Hai-Jun1,2, ZHU Guang-Shan1*, ZHANG Ke-Yong2, SUN Fu-Xing1, QIU Shi-Lun1   

    1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
    2. Department of Pharmacy, Qiqihar Medical University, Qiqihar 161006, China
  • Received:2008-04-23 Revised:1900-01-01 Online:2009-01-10 Published:2009-01-10
  • Contact: ZHU Guang-Shan

摘要: 通过溶剂扩散法成功地将激光染料分子罗丹明B(RhB)组装到了金属有机骨架材料MOF-5中, 从而制备出具有光学活性的主-客体金属有机骨架复合材料RhB/MOF-5. 通过光学显微镜、XRD、FTIR、UV-Vis和PL表征证明RhB存在于MOF-5晶体孔道中, 而且该金属有机骨架复合材料表现出很好的光致发光性质.

关键词: 金属有机骨架化合物, 激光染料, 罗丹明B, 光致发光

Abstract: Metal-organic framework composites RhB/MOF-5 were successfully prepared by diffusion of solvent method. The investigations of Leica microscope, XRD, FTIR, UV-Vis, and photoluminescence confirm the existence of RhB in the pores of MOF-5. The composites which show strong fluorescence could be candidates for applications in optics, especially in laser systems.

Key words: Metal-organic framework(MOF), Laser dye, Rhodamine B, Photoluminescence

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