高等学校化学学报

高等学校化学学报

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C-甲基取代的1-二茂铁酰氧基杂氮硅三环化合物的合成、表征及FcCOOSi(OCHCH3CH2)(OCH2CH2)2N的晶体结构

常卫星, 叶志海, 陈莉, 彭斌, 谢庆兰, 孙丽娟   

  1. 南开大学元素有机化学国家重点实验室, 天津 300071
  • 收稿日期:2006-12-07 修回日期:1900-01-01 出版日期:2007-10-10 发布日期:2007-10-10
  • 通讯作者: 孙丽娟

Synthesis and Characterization of C-Methylsubstituted 1-Ferroceneacyloxysilatranes and Crystal Structure of FcCOOSi(OCHCH3CH2)(OCH2CH2)2N

CHANG Wei-Xing, YE Zhi-Hai, CHEN Li, PENG Bin, XIE Qing-Lan, SUN Li-Juan*   

  1. State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China
  • Received:2006-12-07 Revised:1900-01-01 Online:2007-10-10 Published:2007-10-10
  • Contact: SUN Li-Juan

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摘要： 报道11个新的C-甲基取代的1-二茂铁酰氧基杂氮硅三环化合物.

关键词: 甲基取代, 二茂铁, 杂氮硅三环, 晶体结构

Abstract: As silatranes and its related compounds have specific structures and have been demonstrated to show a significent biological activity, eleven new C-methylsubstituted 1-ferroceneacyloxysilatranes were synthesized via the reaction of ferrocenecarboxylic acids and C-methysubstituted 1-ethoxysilatrans. They were characterized by means of IR, 1H NMR and elemental analysis. X-ray structure determination of compound 1 indicates the presence of N→Si bond with a bond length of 0.2113(4) nm. It belongs to monoclinic system, space group P2(1)/c with a=1.4050(16) nm, b=1.2758(14) nm, c=1.1196(12) nm, α=90°, β=108.598(18)°, γ=90°, Z=4.

Key words: C-Methylsubstitution, Ferrocene, Silatrane, Crystal structure

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