高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (4): 706.

• 研究快报 • 上一篇    下一篇

凝胶网格共沉淀法制备Cu/ZnO/Al2O3合成甲醇催化剂

洪中山, 邓景发, 范康年, 曹勇   

  1. 复旦大学化学系, 上海 200433
  • 收稿日期:2001-11-15 出版日期:2002-04-24 发布日期:2002-04-24
  • 通讯作者: 曹勇(1973年出生),男,博士,副教授,从事多相催化研究.E-mail:yongcao@fudan.edu.cn E-mail:yongcao@fudan.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:29873010);上海市科技发展基金(批准号:0112nm076)资助.

Preparation of Methanol Synthesis Catalyst Cu/ZnO/Al2O3by Gel-network Coprecipitation Method

HONG Zhong-Shan, DENG Jing-Fa, FAN Kang-Nian, CAO Yong   

  1. Department of Chemistry, Fudan University, Shanghai 200433, China
  • Received:2001-11-15 Online:2002-04-24 Published:2002-04-24

关键词: 凝胶网格共沉淀方法, 甲醇合成, 明胶, CO2加氢

Abstract: A novel gel-network-coprecipitation process has been proposed to prepare ultrafine Cu/ZnO/Al2O3 catalysts for methanol synthesis from CO2 hydrogenation.Compared to the catalysts prepared via theconventional coprecipitation method, the new catalysts prepared via gel-network-coprecipitation methodexhibit much higher BETsurface area and metallic copper specific surface area, much smaller crystallitesize and higher catalytic activity and selectivity in CO2 hydrogenation to methanol.The effect of the gelconcentration of gelatin on the structure, morphology and the catalytic properties of the Cu/ZnO/Al2O3catalysts for methanol synthesis from hydrogenation of carbon dioxide were also investigated.

Key words: Gel-network-coprecipitation method, Methanol synthesis, Gelatin polymer, CO2 hydrogena-tion

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