高等学校化学学报

高等学校化学学报 ›› 1997, Vol. 18 ›› Issue (7): 1019.

• 研究快报 • 上一篇    下一篇

三维异双金属混合桥氰化物的合成和结构

张思为1, 段春迎1, 傅得刚1, 唐雯霞1, 胡春华2, 陈健2, 郑培菊2   

  1. 1. 南京大学配位化学国家重点实验室, 南京大学配位化学研究所, 南京 210093;
    2. 复旦大学分析测试中心, 上海 200433
  • 收稿日期:1997-01-28 出版日期:1997-07-24 发布日期:1997-07-24
  • 通讯作者: 唐雯霞.
  • 作者简介:张思为, 男, 34岁, 博士后
  • 基金资助:

    南京大学配位化学国家重点实验资助

Synthesis and Structure of the Three Dimensional Hetero-metallic Cyano Complex with Mixed-bridge

ZHANG Si-Wei1, DUAN Chun-Ying1, FU De-Gang1, TANG Wen-Xia1, HU Chun-Hua2, CHEN Jian2, ZHENG Pei-Ju2   

  1. 1. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjng University, Nanjing 210093;
    2. Research Center of Analysis and Measurement, Fudan University, Shanghai 200433
  • Received:1997-01-28 Online:1997-07-24 Published:1997-07-24

PDF (PC)

被引次数

4

关键词: 三维结构, 异双金属氰化物, 混合桥, 无序

Abstract: The molecular-based magnetic complex {[Cu (1, 3-Pn)]2 [Fe (CN)6] (OH).3H2O }n, where 1, 3-Pn is 1, 3-diaminopropane, has been prepared and characterized by X-raycrystallography.It crystallizes in the monoclinic system, space group P21/n, with a =0.7577(3) nm, b=1.0698(1) nm, c=1.3000(2) nm, β=90.05°, V=1.0538(5) nm3,and Z =4.The result of the crystallography indicates that this complex has a three-dimen-sional structure.

Key words: Three-dimensional structure, Hetero-bimetallic cyano complex, Mixed-bridge, Disorder

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